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Copper nanoparticles synthesized by the polyol method and their oxidation in polar dispersion media. The influence of chloride and acetate ions

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Abstract

Copper nanoparticles have been synthesized from Cu(2+) acetate in the medium of dimethylformamide by the polyol method using hydrazine as a reductant and poly(vinylpyrrolidone) as a stabilizer. Optical spectroscopy has been employed to study the influence of chloride and acetate ions on the oxidation of copper nanoparticles by atmospheric oxygen in aqueous and dimethylformamide media, respectively. It has been established that the presence of ions of one of the aforementioned types in a colloidal solution significantly accelerates the oxidation of metal nanoparticles. In the case of acetate ions, copper oxide particles rapidly dissolve to form the corresponding salt. It has been shown that Cu nanoparticles can be repeatedly formed in such a solution by the addition of hydrazine.

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References

  1. Daniel, M.-C. and Astruc, D., Chem. Rev., 2004, vol. 104, p. 293.

    Article  CAS  Google Scholar 

  2. Krutyakov, Yu.A., Kudrinskii, A.A., Olenin, A.Yu., and Lisichkin, G.V., Usp. Khim., 2008, vol. 77, p. 242.

    Article  Google Scholar 

  3. Xia, Y., Xiong, Y., Lim, B., and Skrabalak, S.E., Angew. Chem., Int. Ed. Engl., 2009, vol. 48, p. 60.

    Article  CAS  Google Scholar 

  4. Magdassi, S., Grouchko, M., and Kamyshny, A., Materials, 2010, vol. 3, p. 4626.

    Article  CAS  Google Scholar 

  5. Pastoriza-Santos, I., Sanchez-Iglesias, A., Rodriguez-Gonzalez, B., and Liz-Marzan, L.M., Small, 2009, vol. 5, p. 440.

    Article  CAS  Google Scholar 

  6. Sarkar, A., Mukherjee, T., and Kapoor, S., J. Phys. Chem. C, 2008, vol. 112, p. 3334.

    Article  CAS  Google Scholar 

  7. Park, B.K., Jeong, S., Kim, D., et al., J. Colloid Interface Sci., 2007, vol. 311, p. 417.

    Article  CAS  Google Scholar 

  8. Jeong, S., Woo, K., Kim, D., et al., Adv. Funct. Mater., 2008, vol. 18, p. 679.

    Article  CAS  Google Scholar 

  9. Huang, H.H., Yan, F.Q., Kek, Y.M., et al., Langmuir, 1997, vol. 13, p. 172.

    Article  CAS  Google Scholar 

  10. Haas, I., Shanmugam, S., and Gedanken, A., J. Phys. Chem. B, 2006, vol. 110, p. 16947.

    Article  CAS  Google Scholar 

  11. Christian, P. and Bromfield, M., J. Mater. Chem., 2010, vol. 20, p. 1135.

    Article  CAS  Google Scholar 

  12. Zhou, G., Lu, M., and Yang, Z., Langmuir, 2006, vol. 22, p. 5900.

    Article  CAS  Google Scholar 

  13. Zhu, H., Zhang, C., and Yin, Y., Nanotechnology, 2005, vol. 16, p. 3079.

    Article  CAS  Google Scholar 

  14. Lisiecki, I., Billoudet, F., and Pileni, M.-P., J. Phys. Chem., 1996, vol. 100, p. 4160.

    Article  CAS  Google Scholar 

  15. Salzemann, C., Lisiecki, I., Brioude, A., et al., J. Phys. Chem. B, 2004, vol. 108, p. 13242.

    Article  CAS  Google Scholar 

  16. Koroleva, M.Yu., Kovalenko, D.A., Shkinev, V.M., et al., Zh. Neorg. Khim., 2011, vol. 56, p. 8.

    Google Scholar 

  17. Tikhonov, A.P., Sorokina, O.N., Kovarskii, A.L., et al., Kolloidn. Zh., 2006, vol. 68, p. 100.

    Google Scholar 

  18. Ershov, B.G. and Abkhalimov, E.V., Kolloidn. Zh., 2009, vol. 71, p. 486.

    Google Scholar 

  19. Saikova, S.V., Vorob’ev, S.A., Nikolaeva, R.B., and Mikhlin, R.Yu., Zh. Obshch. Khim., 2010, vol. 80, p. 952.

    Google Scholar 

  20. Pacioni, N.L., Pardoe, A., McGilvray, K.L., et al., Photochem. Photobiol. Sci., 2010, vol. 9, p. 766.

    Article  CAS  Google Scholar 

  21. Rice, K.P., Walker, E.J., Stoykovich, M.P., and Saunders, A.E., J. Phys. Chem. C, 2011, vol. 115, p. 1793.

    Article  CAS  Google Scholar 

  22. Kanninen, P., Johans, C., Merta, J., and Kontturi, K., J. Colloid Interface Sci., 2008, vol. 318, p. 88.

    Article  CAS  Google Scholar 

  23. Barriere, C., Piettre, K., Latour, V., et al., J. Mater. Chem., 2012, vol. 22, p. 2279.

    Article  CAS  Google Scholar 

  24. Creighton, J.A. and Eadont, D.G., J. Chem. Soc., Faraday Trans., 1991, vol. 87, p. 3881.

    Article  CAS  Google Scholar 

  25. Bardhan, R., Grady, N.K., Ali, T., and Halas, N.J., ACS Nano, 2010, vol. 4, p. 6169.

    Article  CAS  Google Scholar 

  26. Yanase, A., Matsui, H., Tanaka, K., and Komiyama, H., Surf. Sci., 1989, vol. 219, p. L601.

    Article  CAS  Google Scholar 

  27. Wang, Z., Chen, X., Liu, J., et al., Solid State Commun., 2004, vol. 130, p. 585.

    Article  CAS  Google Scholar 

  28. www.nanotechproject.org

  29. Midander, K., Cronholm, P., Karlsson, H.L., et al., Small, 2009, vol. 5, p. 389.

    Article  CAS  Google Scholar 

  30. Schrand, A.M., Rahman, M.F., Hussain, S.M., et al., WIREs Nanomed. Nanobiotechnol., 2010, vol. 2, p. 544.

    Article  CAS  Google Scholar 

  31. Atha, D.H., Wang, H., Petersen, E.J., et al., Environ. Sci. Technol., 2012, vol. 46, p. 1819.

    Article  CAS  Google Scholar 

  32. Wiley, B., Herricks, T., Sun, Y., and Xia, Y., Nano Lett., 2004, vol. 4, p. 1733.

    Article  CAS  Google Scholar 

  33. An, J., Tang, B., Zheng, X., et al., J. Phys. Chem. C, 2008, vol. 112, p. 15176.

    Article  CAS  Google Scholar 

  34. Lessard-Viger, M., Rioux, M., Rainville, L., and Boudreau, D., Nano Lett., 2009, vol. 9, p. 3066.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119071, Russia

    O. V. Dement’eva & V. M. Rudoy

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  1. O. V. Dement’eva
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  2. V. M. Rudoy
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Original Russian Text © O.V. Dement’eva, V.M. Rudoy, 2012, published in Kolloidnyi Zhurnal, 2012, Vol. 74, No. 6, pp. 702–709.

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Dement’eva, O.V., Rudoy, V.M. Copper nanoparticles synthesized by the polyol method and their oxidation in polar dispersion media. The influence of chloride and acetate ions. Colloid J 74, 668–674 (2012). https://doi.org/10.1134/S1061933X1206004X

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  • DOI: https://doi.org/10.1134/S1061933X1206004X

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