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Magnetic susceptibility of nanostructural manganite LaMnO3 + δ produced by mechanochemistry method

  • Magnetism and Ferroelectricity
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Abstract

The mechanochemical method is shown to be a relatively simple method for producing nanostructural manganites LaMnO3 + δ with crystallite size D ≥ 10 nm. An increase in the treatment duration in a planetary mill from 1 to 13 h decreases the size D and increases microstrains. The Curie temperature of the nanostructural manganites decreases insignificantly and the phase transition is smeared as D decreases. A decrease in the unit-cell volume and the temperature dependences of the inverse magnetic susceptibility 1/χ(T) indicate an increase in the Mn4+ ion concentration with the milling duration. The variation of the magnetic properties of LaMnO3 + δ nanostructural powders is explained by the competition of a number factors, such as variations of the composition, the cation-sublattice defect structure, the size effect, and the microstrain level.

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References

  1. E. Dogotto, Nanoscale Phase-Separation and Colossal Magnetoresistance (Springer-Verlag, Berlin, 2002).

    Google Scholar 

  2. O. Yamamoto, Y. Takeda, R. Kanno, and M. Noda, Solid State Ionics 22, 241 (1987).

    Article  Google Scholar 

  3. P. E. Marti and A. Baiker, Catal. Lett. 26, 71 (1994).

    Article  ADS  Google Scholar 

  4. E. Rosenberg, G. Jung, M. Auslender, G. Gorodetsky, I. Felner, E. Sominski, A. Gedanken, and Ya. M. Mukovskii, J. Appl. Phys. 99, 08Q305 (2006).

    Google Scholar 

  5. L. Malavasi, M. C. Mozzati, S. Polizzi, C. B. Azzoni, and G. Flor, Chem. Mater. 15, 5036 (2003).

    Article  Google Scholar 

  6. V. Krivoruchko, T. Konstantinova, A. Mazur, A. Prokhorov, and V. Varyukin, J. Magn. Magn. Mater. 300, e122 (2005).

    Article  Google Scholar 

  7. K. S. Shankar, S. Kar, G. N. Subbanna, and A. K. Raychaudhuri, Solid State Commun. 129, 479 (2004).

    Article  ADS  Google Scholar 

  8. Yu. A. Koksharov, V. N. Nikiforov, V. D. Kuznetsov, and G. B. Khomutov, Microelectron. Eng. 81, 371 (2005).

    Article  Google Scholar 

  9. J. Rivas, L. E. Hueso, A. Fondado, F. Rivadulla, and M. A. Lopez-Quintela, J. Magn. Magn. Mater. 221, 57 (2000).

    Article  ADS  Google Scholar 

  10. F. Chen, H. F. Liu, K. F. Wang, H. Yu, S. Dong, X. Y. Chen, X. P. Jiang, Z. F. Ren, and J.-M. Liu, J. Phys.: Condens. Mater 17, L467 (2005).

    Article  ADS  Google Scholar 

  11. T. I. Arbuzova, S. V. Naumov, and E. A. Kozlov, Fiz. Tverd. Tela (St. Petersburg) 47(7), 1309 (2005) [Phys. Solid State 47 (7), 1358 (2005)].

    Google Scholar 

  12. T. I. Arbuzova, S. V. Naumov, E. A. Kozlov, V. L. Arbuzov, K. V. Shal’nov, B. A. Gizhevskiĭ, Yu. G. Chukalkin, and V. I. Voronin, Zh. Éksp. Teor. Fiz. 129(6), 1056 (2006) [JETP 102 (6), 931 (2006)].

    Google Scholar 

  13. J. Rodriguez-Carvajal, Physica B (Amsterdam) 192, 55 (1993).

    ADS  Google Scholar 

  14. P. Thompson, D. E. Cox, and J. B. Hastings, J. Appl. Crystallogr. 20, 79 (1987).

    Article  Google Scholar 

  15. J. A. M. van Roosmalen, P. van Vlaanderen, E. H. P. Cordfunke, W. L. Ijodo, and D. J. W. Ijdo, J. Solid State Chem. 114, 516 (1995).

    Article  Google Scholar 

  16. B. A. Gizhevskiĭ, V. R. Galakhov, D. A. Zatsepin, L. V. Elokhina, T. A. Belykh, E. A. Kozlov, S. V. Naumov, V. L. Arbuzov, K. V. Shal’nov, and M. Neumann, Fiz. Tverd. Tela (St. Petersburg) 44(7), 1318 (2002) [Phys. Solid State 44 (7), 1380 (2002)].

    Google Scholar 

  17. R. H. Kodama and A. E. Berkowitz, Phys. Rev. B: Condens. Matter 59, 6321 (1999).

    ADS  Google Scholar 

  18. J. B. Goodenough, Magnetism and the Chemical Bond (Wiley, New York, 1963; Metallurgiya, Moscow, 1968).

    Google Scholar 

  19. M. Hehnion, F. Moussa, G. Giotteau, J. Rodriguez-Carvajal, L. Pinsard, and A. Revcolevschi, Phys. Rev. Lett. 81, 1957 (1998).

    Article  ADS  Google Scholar 

  20. J. S. Smart, Effective Field Theories of Magnetism (Saunders, Philadelphia, PA, United States, 1966; Mir, Moscow, 1968).

    Google Scholar 

  21. S. de Brion, F. Ciorcas, G. Chouteau, P. Lejay, P. Radaelli, and C. Chaillout, Phys. Rev. B: Condens. Matter 59, 1304 (1999).

    ADS  Google Scholar 

  22. X. Vang and F. Freeman, J. Magn. Magn. Mater. 171, 103 (1997).

    Article  ADS  Google Scholar 

  23. P. K. Baltzer and P. J. Wojtowicz, Phys. Rev. 151, 367 (1966).

    Article  ADS  Google Scholar 

  24. Q. Huang, A. Sautoro, J. W. Lynn, and R. W. Erwin, Phys. Rev. B: Condens. Matter 55, 14 987 (1997).

    Google Scholar 

  25. N. N. Loshkareva, N. I. Solin, Yu. P. Sukhorukov, N. I. Lobachevskaya, and E. V. Panfilova, Physica B (Amsterdam) 293, 390 (2001).

    ADS  Google Scholar 

  26. G. Dezahhean, M. Audier, H. Vincent, C. Meneghini, and E. Durado, Phys. Rev. B: Condens. Matter 69, 014412 (2004).

    Google Scholar 

  27. J. A. Alonso, M. J. Martinez-Lope, M. T. Casais, and A. Munoz, Solid State Commun. 102, 7 (1997).

    Article  ADS  Google Scholar 

  28. L. Ghivelder, I. Abrego Castillo, M. A. Gusmao, J. A. Alonso, and L. F. Cohen, Phys. Rev. B: Condens. Matter 60, 12 184 (1999).

    Google Scholar 

  29. R. Laiho, K. G. Lisunov, E. Lähderanta, P. A. Petrenko, J. Salminen, V. N. Stamon, Yu. P. Stepanov, and V. S. Zakhavalinskii, J. Phys. Chem. Solids 64, 2313 (2003).

    Article  ADS  Google Scholar 

  30. A. I. Gusev, Nanocrystalline Materials: Techniques of Preparation and Properties (Ural Division of the Russian Academy of Sciences, Yekaterinburg, 1998) [in Russian].

    Google Scholar 

  31. G. Dezannea, A. Sin, H. Roussel, H. Vincent, and M. Audier, Solid State Commun. 121, 133 (2002).

    Article  ADS  Google Scholar 

  32. S. Roy, I. Dubenko, D. D. Edorh, and N. Ali, J. Appl. Phys. 96, 1202 (2004).

    Article  ADS  Google Scholar 

  33. R. Mahesh, R. Mahendian, A. K. Raychaudhuri, and C. N. R. Rio, Appl. Phys. Lett. 68, 2291 (1996).

    Article  ADS  Google Scholar 

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Authors and Affiliations

  1. Institute of Metal Physics, Ural Division, Russian Academy of Sciences, ul. S. Kovalevskoĭ 18, Yekaterinburg, 620041, Russia

    T. I. Arbuzova, B. A. Gizhevskiĭ & N. M. Chebotaev

  2. Institute of Metallurgy, Ural Division, Russian Academy of Sciences, ul. Amundsena 101, Yekaterinburg, 620016, Russia

    R. G. Zakharov & S. A. Petrova

Authors
  1. T. I. Arbuzova
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  2. B. A. Gizhevskiĭ
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  3. R. G. Zakharov
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  4. S. A. Petrova
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  5. N. M. Chebotaev
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Correspondence to B. A. Gizhevskiĭ.

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Original Russian Text © T.I. Arbuzova, B.A. Gizhevskiĭ, R.G. Zakharov, S.A. Petrova, N.M. Chebotaev, 2008, published in Fizika Tverdogo Tela, 2008, Vol. 50, No. 8, pp.1430–1437.

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Arbuzova, T.I., Gizhevskiĭ, B.A., Zakharov, R.G. et al. Magnetic susceptibility of nanostructural manganite LaMnO3 + δ produced by mechanochemistry method. Phys. Solid State 50, 1487–1494 (2008). https://doi.org/10.1134/S1063783408080179

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  • DOI: https://doi.org/10.1134/S1063783408080179

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