Skip to main content
SpringerLink
Log in

Complexes [Cu(H2L)](NO3)2 and [Cu(H2L)Cl]2[CuCl2]Cl · 0.5H2O (H2L is chiral bis(menthane) propylenediaminodioxime): Synthesis and structure

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

The synthesis of the [Cu(H2L)](NO3)2 complex (I) and of a mixed-valent complex [Cu(H2L)Cl]2[CuCl2]Cl·0.5H2O (II), where L is chiral bis(menthane) propylenediaminodioxime. According to the data of single-crystal X-ray diffraction analysis, compounds I and II have ionic structures. In complex cations, the Cu2+ ion coordinates four N atoms of tetradentate chelate ligand, namely, the H2L molecule. The coordination surrounding of the Cu atom in I is a distorted square CuN4, while in II, it is a distorted square pyramid CuN4Cl. The complex anion [CuCl2]− in II has linear structure. The mutual arrangement of oxime groups in H2L corresponds to amphi-configuration of a ligand and therefore, intramolecular hydrogen bond O...H-O are formed in H2L. The complex cations in compound II are joined in dimers through hydrogen bonds Cl...H-O. The values μeff for I and II are equal to 1.82 and 2.82 μB, respectively.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Von Zelewsky, A. and Mamula, O., J. Chem. Soc., Dalton Trans., 2000, no. 3, p. 219.

  2. Mamula, O. and von Zelewsky, A., Coord. Chem. Rev., 2003, vol. 242, nos. 1–2, p. 87.

    Article  CAS  Google Scholar 

  3. Larionov, S.V. and Tkachev, A.V., Ross. Khim. Zh., 2004, vol. 48, no. 4, p. 154.

    CAS  Google Scholar 

  4. Tkachev, A.V., Ross. Khim. Zh., 1998, vol. 42, nos. 1–2, p. 42.

    CAS  Google Scholar 

  5. Larionov, S.V., Myachina, L.I., Sheludyakova, L.A., et al., Koord. Khim., 2004, vol. 30, no. 12, p. 897.

    Google Scholar 

  6. Larionov, S.V., Savel’eva, Z.A., Glinskaya, L.A., et al., Koord. Khim., 2006, vol. 32, no. 5, p. 365.

    Google Scholar 

  7. Larionov, S.V., Tkachev, A.V., Savel’eva, Z.A., et al., Koord. Khim., 2006, vol. 32, no. 4, p. 261.

    Google Scholar 

  8. Sheldrick, G.M., SHELX97. Release 97-2, Göttingen (Germany): Univ. of Göttingen, 1998.

    Google Scholar 

  9. Marsh, W.C. and Trotter, J., J. Chem. Soc., A, 1971, no. 10, p. 1482.

  10. Reid, K.F., Properties and Reactions of Bonds in Organic Molecules, London: Longmans, 1968.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    Z. A. Savel’eva, R. F. Klevtsova, L. A. Glinskaya, V. N. Ikorskii & S. V. Larionov

  2. Novosibirsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    S. N. Bizyaev & A. V. Tkachev

Authors
  1. Z. A. Savel’eva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. R. F. Klevtsova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. A. Glinskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. N. Ikorskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. S. N. Bizyaev
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. V. Tkachev
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. S. V. Larionov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © Z.A. Savel’eva, R.F. Klevtsova, L.A. Glinskaya, V.N. Ikorskii, S.N. Bizyaev, A.V. Tkachev, S.V. Larionov, 2006, published in Koordinatsionnaya Khimiya, 2006, Vol. 32, No. 11, pp. 816–822.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Savel’eva, Z.A., Klevtsova, R.F., Glinskaya, L.A. et al. Complexes [Cu(H2L)](NO3)2 and [Cu(H2L)Cl]2[CuCl2]Cl · 0.5H2O (H2L is chiral bis(menthane) propylenediaminodioxime): Synthesis and structure. Russ J Coord Chem 32, 784–791 (2006). https://doi.org/10.1134/S1070328406110030

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328406110030

Keywords

Search

Navigation