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A study of solid-state rhodium(III) sulfates

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Abstract

Solid-state rhodium(III) sulfates and their aqueous solutions were examined by IR and electronic absorption spectroscopy, thermogravimetry, X-ray powder diffraction analysis, and 103Rh and 17O NMR spectroscopy. A study of the spontaneous aquation of freshly prepared solutions showed that this process results in an equilibrium between the subsystems of monomeric and oligomeric complexes. It was found that solid-state rhodium(III) sulfates vary in phase composition, basically consisting of dimeric and trimeric complexes.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    S. N. Shagabutdinova & A. V. Belyaev

  2. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 5, Novosibirsk, 630090, Russia

    M. A. Fedotov

  3. OAO Krastsvetmet, Krasnoyarsk, Russia

    V. D. Il’yashevich & E. I. Pavlova

Authors
  1. S. N. Shagabutdinova
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  2. M. A. Fedotov
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  3. A. V. Belyaev
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  4. V. D. Il’yashevich
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  5. E. I. Pavlova
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Corresponding author

Correspondence to A. V. Belyaev.

Additional information

Original Russian Text © S.N. Shagabutdinova, M.A. Fedotov, A.V. Belyaev, V.D. Il’yashevich, E.I. Pavlova, 2008, published in Koordinatsionnaya Khimiya, 2008, Vol. 34, No. 12, pp. 930–936.

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Shagabutdinova, S.N., Fedotov, M.A., Belyaev, A.V. et al. A study of solid-state rhodium(III) sulfates. Russ J Coord Chem 34, 917–923 (2008). https://doi.org/10.1134/S1070328408120087

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  • DOI: https://doi.org/10.1134/S1070328408120087

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