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Formation of the heteropolynuclear complex ([NH2(C4H9)2][Au{S2CN(C4H9)2}2][CdCl4]) n during the chemisorption of gold(III) with cadmium dibutyldithiocarbamate: Structure and thermal properties

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Abstract

The chemisorption properties of cadmium dibutyldithiocarbamate with respect to [AuCl4]− in 2M HCl solutions are studied. The heterogeneous reaction of gold(III) binding affords the heteropolynuclear compound ([NH{2(C4H9)2][Au{S2CN(C4H9)2}2][CdCl4]) n (I). The molecular and crystal structures of compound I are determined from the X-ray diffraction data. Each of three ions is presented in the structure by two conformers. The irreversible decomposition of some dibutyldithiocarbamate groups is observed during the chemisorption of gold(III), which noticeably decreases the efficiency of gold binding with the sorbent studied and its sorption capacity. The study of the thermal properties of compound I shows that gold(III) is reduced to the metal during thermolysis.

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Authors and Affiliations

  1. Institute of Geology and Nature Management, Far East Division, Russian Academy of Sciences, Blagoveshchensk, 675000, Russia

    A. V. Ivanov, O. V. Loseva & A. S. Zaeva

  2. Institute of Chemistry, Far East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022, Russia

    V. I. Sergienko & A. V. Gerasimenko

Authors
  1. A. V. Ivanov
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  2. V. I. Sergienko
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  3. A. V. Gerasimenko
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  4. O. V. Loseva
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  5. A. S. Zaeva
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Correspondence to A. V. Ivanov.

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Original Russian Text © A.V. Ivanov, V.I. Sergienko, A.V. Gerasimenko, O.V. Loseva, A.S. Zaeva, 2010, published in Koordinatsionnaya Khimiya, 2010, Vol. 36, No. 5, pp. 353–358.

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Ivanov, A.V., Sergienko, V.I., Gerasimenko, A.V. et al. Formation of the heteropolynuclear complex ([NH2(C4H9)2][Au{S2CN(C4H9)2}2][CdCl4]) n during the chemisorption of gold(III) with cadmium dibutyldithiocarbamate: Structure and thermal properties. Russ J Coord Chem 36, 353–358 (2010). https://doi.org/10.1134/S1070328410050064

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  • DOI: https://doi.org/10.1134/S1070328410050064

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