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Metal complexes with azomethines containing the isomeric E-Z azo fragments

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Abstract

Cobalt and zinc complexes with phenylazosalicylaldehyde azomethines were obtained by chemical and electrochemical syntheses. The B3LYP/6-311G(d, p) calculations showed that the azo group in both the ligands and the complexes are mainly in the E-form.

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Correspondence to A. D. Garnovskii.

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Original Russian Text © A.D. Garnovskii, A.S. Burlov, A.G. Starikov, A.V. Metelitsa, I.S. Vasil’chenko, S.O. Bezugliy, S.A. Nikolaevskii, I.G. Borodkina, V.I. Minkin, 2010, published in Koordinatsionnaya Khimiya, 2010, Vol. 36, No. 7, pp. 483–493.

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Garnovskii, A.D., Burlov, A.S., Starikov, A.G. et al. Metal complexes with azomethines containing the isomeric E-Z azo fragments. Russ J Coord Chem 36, 479–489 (2010). https://doi.org/10.1134/S1070328410070018

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  • DOI: https://doi.org/10.1134/S1070328410070018

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