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Zinc and cadmium complexes based on 3,6-di-tert-butyl-o-benzoquinone

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Abstract

Zinc and cadmium bis-o-semuquinolate and catecholate complexes are synthesized by the reduction of 3,6-di-tert-butyl-o-benzoquinone (3,6-Q) with amalgamated metals in a medium of various solvents. The oxidation of the metal catecholate derivatives results in the corresponding mono-o-semiquinone complexes, which undergo symmetrization to form the metal bis-o-semiquinolates. The molecular structures of the complexes (3,6-SQ)2Zn · Py, (3,6-SQ)2Zn · H2O, and (3,6-SQ)2Cd · α,α′-Bipy (3,6-SQ is the radical anion of 3,6-Q) are studied by X-ray diffraction analysis. Magnetochemical studies are carried out for the zinc and cadmium bis-o-semiquinone complexes.

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Authors and Affiliations

  1. Institute of Organometallic Chemistry, Russian Academy of Sciences, ul.Tropinina 49, Nizhnii Novgorod, 603600, Russia

    A. V. Piskunov, A. V. Maleeva, G. A. Abakumov, V. K. Cherkasov & G. K. Fukin

  2. International Tomography Center, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, 630090, Russia

    A. S. Bogomyakov

Authors
  1. A. V. Piskunov
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  2. A. V. Maleeva
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  3. G. A. Abakumov
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  4. V. K. Cherkasov
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  5. G. K. Fukin
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  6. A. S. Bogomyakov
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Correspondence to A. V. Piskunov.

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Original Russian Text © A.V. Piskunov, A.V. Maleeva, G.A. Abakumov, V.K. Cherkasov, G.K. Fukin, A.S. Bogomyakov, 2011, published in Koordinatsionnaya Khimiya, 2011, Vol. 37, No. 4, pp. 243–255.

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Piskunov, A.V., Maleeva, A.V., Abakumov, G.A. et al. Zinc and cadmium complexes based on 3,6-di-tert-butyl-o-benzoquinone. Russ J Coord Chem 37, 243–256 (2011). https://doi.org/10.1134/S1070328411030092

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  • DOI: https://doi.org/10.1134/S1070328411030092

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