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Molecular Complex of Cadmium(II) Trifluoroacetate with Triphenylphosphine: Crystal Structure and Luminescence Properties

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Abstract

Cadmium compound [Cd(CF3COO)2(Ph3P)2] is synthesized, and its crystal structure is determined. The crystals are monoclinic: space group C2/c, a = 20.318(4), b = 10.432(2), c = 18.661(4) Å, β = 104.18(1)°, V = 3834.8(13) Å3, Z = 4, ρcalcd = 1.495 g/cm3. The Cd atom arranged on the 2-fold crystallographic axis has a distorted octahedral coordination due to four oxygen atoms of crystallographically equivalent trifluoroacetate ligands and two phosphorus atoms of triphenylphosphine. Each fluorine atom of the trifluoroacetate groups is randomly disordered over three equally probable positions. The compound is luminescent.

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Funding

This work was supported by the state task of the Kurnakov Institute of General and Inorganic Chemistry (Russian Academy of Sciences) in the area of basic research.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    Yu. V. Kokunov, V. V. Kovalev, Yu. E. Gorbunova, A. V. Churakov & S. A. Kozyukhin

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  1. Yu. V. Kokunov
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  2. V. V. Kovalev
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  3. Yu. E. Gorbunova
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  4. A. V. Churakov
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  5. S. A. Kozyukhin
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Correspondence to V. V. Kovalev.

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Translated by E. Yablonskaya

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Kokunov, Y.V., Kovalev, V.V., Gorbunova, Y.E. et al. Molecular Complex of Cadmium(II) Trifluoroacetate with Triphenylphosphine: Crystal Structure and Luminescence Properties. Russ J Coord Chem 45, 473–477 (2019). https://doi.org/10.1134/S1070328419070042

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  • DOI: https://doi.org/10.1134/S1070328419070042

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