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Specific features of the reaction of vanadyl acetylacetonate with tert-butyl hydroperoxide

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Abstract

Reaction of vanadyl acetylacetonate with tert-butyl hydroperoxide (benzene, 20°C) at any molar ratio leads to the elimination of ligand and its oxidation mainly to CO2 and acetic acid. At the (acac)2VO: t-BuOOH ratio above 1:10 liberation of oxygen partially in the singlet state takes place.

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Authors and Affiliations

  1. Lobachevskii Nizhnii Novgorod State University, pr. Gagarina 23, Nizhnii Novgorod, 603950, Russia

    L. P. Stepovik & M. V. Gulenova

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  1. L. P. Stepovik
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  2. M. V. Gulenova
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Correspondence to M. V. Gulenova.

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Original Russian Text © L.P. Stepovik, M.V. Gulenova, 2009, published in Zhurnal Obshchei Khimii, 2009, Vol. 79, No. 8, pp. 1304–1310.

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Stepovik, L.P., Gulenova, M.V. Specific features of the reaction of vanadyl acetylacetonate with tert-butyl hydroperoxide. Russ J Gen Chem 79, 1663–1670 (2009). https://doi.org/10.1134/S1070363209080143

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