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Reaction of metal exchange of cadmium 5,10,15,20-tetraphenylporphyrinate and its β-bromo derivative with zinc acetate in dimethylformamide

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Abstract

Metal exchange of cadmium 5,10,15,20-tetraphenylporphyrinate (CdTPP) and cadmium 2-bromo-5,10,15,20-tetraphenylporphyrinate (CdTPPBr) with zinc acetate in dimethylformamide was spectrophotometrically examined. The kinetic parameters of the metal exchange reaction were determined. A possible stoichiometric mechanism of the reaction was suggested. The effect of the bromo substituent in β-position of the pyrrole in the cadmium tetraphenylporphyrinate on the metal exchange reaction with Zn(OAc)2 in DMF was found.

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Authors and Affiliations

  1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153040, Russia

    S. V. Zvezdina, N. V. Chizhova & N. Zh. Mamardashvili

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  1. S. V. Zvezdina
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  2. N. V. Chizhova
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  3. N. Zh. Mamardashvili
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Correspondence to S. V. Zvezdina.

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Original Russian Text © S.V. Zvezdina, N.V. Chizhova, N.Zh. Mamardashvili, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 5, pp. 855–858.

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Zvezdina, S.V., Chizhova, N.V. & Mamardashvili, N.Z. Reaction of metal exchange of cadmium 5,10,15,20-tetraphenylporphyrinate and its β-bromo derivative with zinc acetate in dimethylformamide. Russ J Gen Chem 83, 989–992 (2013). https://doi.org/10.1134/S1070363213050198

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  • DOI: https://doi.org/10.1134/S1070363213050198

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