Abstract
Ecologically safe effective catalytic method for preparing phosphorous and phosphoric acid esters by oxidation of zinc phosphide with oxygen in the solution of copper(II) halides in butanol at 50–70°C is developed. It is found that in the presence of Cu(II) chloride a mixture of dibutyl hydrogen phosphite and tributyl phosphate is formed, while at the catalysis with Cu(II) bromide tributyl phosphate is mainly obtained. Promoting action of hydrogen chloride on the reaction rate and yield of organophosphorus compounds is established. Optimal reaction conditions are found and redox mechanism of catalytic process is assumed.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Tekhnologiya fosfora (Phosphorus Technology), Belov, V.N., Bol’shakova, A.P., and Dantsis, Ya.B., Eds., Leningrad: Khimiya, 1979.
Chernogorenko, V.B., Novoe v poluchenii i primenenii fosfidov i fosforsoderzhashchikh splavov (New Aspects of Obtaining and Use of Phosphides and Phosphorus-Containing Melts), Alma-Ata: Nauka, 1988, vol. 1, p. 5.
Meyer, T., Honle, W., and Von Schnering, H.G., Z. Anorg. Allg. Chem., 1987, vol. 552, p. 69.
Trofimov, B.A., Brandsma, L., Arbuzova, S.N., Malysheva, S.F., and Gusarova, N.K., Tetrahedron Lett., 1994, vol. 35, no. 41, p. 7647.
Trofimov, B.A., Arbuzova, S.N., and Gusarova, T.N., Usp. Khim., 1999, vol. 68, no. 3, p. 240.
Ibraimova, Zh. U., Polimbetova, G.S., Aleshkova, M.M., and Borangazieva, A.K., Zh. Fiz. Khim., 2004, vol. 78, no. 8, p. 1443.
Ibraimova, Zh.U., Polimbetova, G.S., Aleshkova, M.M., and Borangazieva, A.K., Zh. Fiz. Khim., 2009, vol. 83, no. 5, p. 852.
Purdela, D. and Vylchanu, R., Khimiya organicheskikh soedinenii fosfora (Chemistry of Organophosphorus Compounds), Moscow: Khimiya, 1972.
Nifant’ev, E.E. and Vasyanina, L.K., Spektroskopiya 31 P (31P NMR Spectroscopy), Moscow: MGPI, 1986.
Atlas IK-spectrov fosfororganicheskikh soedinenii (Atlas of IR spectra of Organophosphorus Compounds), Pudovik, A.N., Ed., Moscow: Nauka, 1977.
Temkin, O.N., Gomogennyi metallokompleksnyi kataliz. Kineticheskie aspekty (Homogenic Metal Complex Catalysis. Kinetic Aspects), Moscow: Akademkniga, 2008.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © G.S. Polimbetova, Zh.U. Ibraimova, A.K. Borangazieva, 2013, published in Zhurnal Obshchei Khimii, 2013, Vol. 83, No. 6, pp. 950–955.
Rights and permissions
About this article
Cite this article
Polimbetova, G.S., Ibraimova, Z.U. & Borangazieva, A.K. Catalytic method of synthesis of phosphorus acids esters from zinc phosphide and alcohol. Russ J Gen Chem 83, 1081–1086 (2013). https://doi.org/10.1134/S1070363213060133
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363213060133