Abstract
Hydroalumination-iodination of alkyne-1,4-diols of different structure showed that with increasing number of substituents at the C-OH group the amount of β-iodo-substituted products with respect to this group increased. In the case of symmetric secondary 1,4-diols the reaction results in a 1: 1 mixture of stereoisomeric iodoalkenediols, and in the case of phenyl substituents the reaction proceeds regio- and stereoselectively to give an alkenediol iodine atom in the β-position to phenyl group.
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Original Russian Text © H.A. Gharibyan, G.M. Makaryan, M.R. Hovhannisyan, F.S. Kinoyan, Zh.A. Chobanyan, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 3, pp. 399–406.
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Gharibyan, H.A., Makaryan, G.M., Hovhannisyan, M.R. et al. Some special features of hydroalumination-iodination of alkyne-1,4-diols. Russ J Gen Chem 84, 457–464 (2014). https://doi.org/10.1134/S1070363214030086
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DOI: https://doi.org/10.1134/S1070363214030086