Skip to main content
SpringerLink
Log in

Recovery of lanthanides from digested phosphogypsum solutions using a new organophosphorus extractant, 5-(diphenylphosphoryl)hexan-3-one

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Extraction of rare earth elements from digested phosphogypsum solutions with a number of well-known organophosphorus compounds, tributyl phosphate, trioctylphosphine oxide, and bis(2-ethylhexyl)-phosphoric acid, as well as with phosphoryl ketone Ph2P(O)CHMeCH2C(O)Et, was studied. It was found that this phosphoryl ketone is the most effective reagent for obtaining the mixed lanthanide concentrate. An improved synthetic route to this compound was developed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Abramov, A.M., Galieva, Zh.N., Galiev, R.S., and Sobol’, Yu.B., RF Patent 2487834, Byull. Izobret., 2013, no. 20.

  2. Kolyasnikov, S.V., Borisov, M.M., Kirillov, E.V., and Rybina, M.L., RF Patent 2471011, Byull. Izobret., 2012, no. 36.

  3. Ryabinskii, A.M., Kopylkov, A.M., Kantsel’, A.V., Mazurkevich, P.A., Salov, A.A., and Netreba, V.N., RF Patent 2526907, Byull. Izobret., 2014, no. 24.

  4. Val’kov, A.V., RF Patent 2525877, Byull. Izobret., 2014, no. 23.

  5. Bashlykova, T.V., Val’kov, A.V., and Petrov, V.I., Tsvetn. Met., 2012, no. 3, p. 40.

    Google Scholar 

  6. Malikov, V.A. and Krylova, O.K., Tsvetn. Met., 2003, no. 4, p. 63.

    Google Scholar 

  7. Kosynkin, V.D., Selivanovskii, A.K., Fedulova, T.T., Smirnov, K.M., and Krylova, O.K., Tsvetn. Met., 2012, no. 3, p. 31.

    Google Scholar 

  8. Genkin, M.V., Evtushenko, A.V., Komkov, A.A., Safiulina, A.M., Spiridonov, V.S, and Shvetsov, S.V., RF Patent 2528573, Byull. Izobret., 2014, no. 26.

  9. Genkin, M.V., Evtushenko, A.V., Komkov, A.A., Safiulina, A.M., Spiridonov, V.S, and Shvetsov, S.V., RF Patent 2528576, Byull. Izobret., 2014, no. 26.

  10. Kolokol’nikov, V.A., Titov, V.M., and Shatov, A.A., RF Patent 2258036, Byull. Izobret., 2005, no. 22.

  11. Preston, J.S., Cole, P.M, Craig, W.M., and Feather, A.M., Hydrometallurgy, 1996, vol. 41, no. 1, p. 1. DOI. 10.1016/0304-386X(95)00051-H.

    Article  CAS  Google Scholar 

  12. Wang, L., Long, Z., Huang, X., Yu, Y., Cui, D., and Zhang, G., Hydrometallurgy, 2010, vol. 101, nos. 1–2, p. 41. DOI. 10.1016/j.hydromet.2009.11.017.

    Article  CAS  Google Scholar 

  13. Krea, M. and Khalaf, H., Hydrometallurgy, 2000, vol. 58, no. 3, p. 215. DOI. 10.1016/S0304-386X(00)00129-8.

    Article  CAS  Google Scholar 

  14. Al-Thyabat, S. and Zhang, P., Hydrometallurgy, 2015, vol. 153, p. 30. DOI. 10.1016/j.hydromet.2015.01.010.

    Article  CAS  Google Scholar 

  15. Zhu, Z., Pranolo, Y., and Cheng, C.Y., Miner. Eng., 2015, vol. 77, p. 185. DOI. 10.1016/j.mineng.2015.03.012.

    Article  CAS  Google Scholar 

  16. Xie, F., Zhang, T.A., Dreisinger, D., and Doyle, F., Miner. Eng., 2014, vol. 56, p. 10. DOI. 10.1016/j.mineng.2013.10.021.

    Article  CAS  Google Scholar 

  17. Al-Thyabat, S. and Zhang, P., Miner. Proc. Extract. Metall., 2015, vol. 124, no. 3, p. 143. DOI. 10.1179/1743285515Y.0000000002.

    Article  CAS  Google Scholar 

  18. Safiulina, A.M., Matveeva, A.G., Dvoryanchikova, T.K., Sinegribova, O.A., Tu, A.M., Tatarinov, D.A., Kostin, A.A., Mironov, V.F., and Tananaev, I.G., Russ. Chem. Bull., Int. Ed., 2012, vol. 61, no. 2, p. 392. DOI. 10.1007/s11172-012-0055-0.

    Article  CAS  Google Scholar 

  19. Matveeva, A.G., Tu, A.M., Safiulina, A.M., Bodrin, G.V., Goryunov, E.I., Goryunova, I.B., Sinegribova, O.A., and Nifant’ev, E.E., Russ. Chem. Bull., Int. Ed., 2013, vol. 62, no. 6, p. 1309. DOI. 10.1007/s11172-013-0184-0.

    Article  CAS  Google Scholar 

  20. Matveeva, A.G., Goryunov, E.I., Tu, A.M., Safiulina, A.M., Goryunova, I.B., Bodrin, G.V., Lesiv, A.V., Sinegribova, O.A., and Brel, V.K., Russ. Chem. Bull., Int. Ed., 2014, vol. 63, no. 11, p. 2493. DOI. 10.1007/s11172- 014-0767-4.

    Article  CAS  Google Scholar 

  21. Safiulina, A.M., Matveeva, A.G., Lizunov, A.V., Bodrin, G.V., Goryunov, E.I., Grigor’ev, M.S., Semenov, A.A., Brel, V.K., and Nifant’ev, E.E., Dokl. Chem., 2015, vol. 460, part 2, p. 57. DOI. 10.7868/S0869565215060146.

    Article  CAS  Google Scholar 

  22. Khimiya i tekhnologiya redkikh i rasseyannykh elementov (Chemistry and Technology of Rare and Scattered Elements), Bol’shakov, K.A., Ed., Moscow: Vysshaya Shkola, 1976, par. 2.

  23. Ion Exchange and Solvent Extraction: A Series of Advances, Moyer, B.A., Ed., Boca Raton: CRC, 2010, vol. 19.

  24. Kislik, V.S., Solvent Extraction: Classical and Novel Approaches, Oxford: Elsevier, 2012.

    Google Scholar 

  25. A Book on Ion Exchange, Adsorption and Solvent Extraction (Chemistry Research and Applications), Naushad, M. and Al-Othman, Z.A., Eds., New York: Nova Science, 2013.

  26. Mastryukova, T.A., Artyushin, O.I., Odinets, I.L., and Tananaev, I.G., Ross. Khim. Zh., 2005, vol. 49, no. 2, p. 86.

    CAS  Google Scholar 

  27. Rozen, A.M. and Krupnov, B.V., Russ. Chem. Rev., 1996, vol. 65, p. 973. DOI. 10.1070/RC1996v065n11ABEH000241.

    Article  Google Scholar 

  28. Sharova, E.V., Artyushin, O.I., and Odinets, I.L., Russ. Chem. Rev., 2014, vol. 83, no. 1, p. 95. DOI. 10.1070/RC2014v083n02ABEH004384.

    Article  Google Scholar 

  29. Pereira, F. and Bilal, E., Roman. J. Mineral Dep., 2012, vol. 85, no. 2, p. 49.

    Google Scholar 

  30. Sato, T., Hydrometallurgy, 1989, vol. 22, p. 121. DOI. 10.1016/0304-386X(89)90045-5.

    Article  CAS  Google Scholar 

  31. Parhi, P.K., Park, K.H., Nam, C.W., and Park, J.T., J. Rare Earths, 2015, vol. 33, no. 2, p. 207. DOI. 10.1016/S1002-0721(14)60404-X.

    Article  CAS  Google Scholar 

  32. Tong, H., Wang, Y., Liao, W., and Li, D., Sep. Pur. Technol., 2013, vol. 118, p. 487. DOI. 10.1016/j.seppur.2013.07.039.

    Article  CAS  Google Scholar 

  33. Xiong, Y., Wang, X., and Li, D., Sep. Sci. Technol., 2005, vol. 40, p. 2325. DOI. 10.1080/01496390500202472.

    Article  CAS  Google Scholar 

  34. Bunus, F., Miu, I., and Dumitrescu, R., Hydrometallurgy, 1994, vol. 35, no. 3, p. 375. DOI. 10.1016/0304-386X(94)90063-9.

    Article  CAS  Google Scholar 

  35. Khitrova, O.A., RF Patent 2511375, 2014, Byull. Izobret., no. 10, 2014.

  36. GOST (State Standard) 23862.0-17, GOST 23862.36-79: Rare Earth Metals and Their Oxides: Methods of Analysis, Moscow: Izd. Standartov, 2003.

Download references

Author information

Authors and Affiliations

  1. Uralchem United Chemical Company, Open Joint-Stock Company, Presnenskaya nab. 6/2, Moscow, 123317, Russia

    A. M. Safiulina & A. V. Evtushenko

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia

    A. G. Matveeva, E. I. Goryunov, I. B. Goryunova, G. V. Bodrin & V. K. Brel

  3. Bochvar High-Technology Research Institute of Inorganic Materials, Open Joint-Stock Company, Rosatom State Atomic Energy Corporation, ul. Rogova 5a, Moscow, 123098, Russia

    A. V. Lizunov & A. A. Semenov

Authors
  1. A. M. Safiulina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. G. Matveeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. V. Evtushenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. V. Lizunov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. E. I. Goryunov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. I. B. Goryunova
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. G. V. Bodrin
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. A. A. Semenov
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. V. K. Brel
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. G. Matveeva.

Additional information

Original Russian Text © A.M. Safiulina, A.G. Matveeva, A.V. Evtushenko, A.V. Lizunov, E.I. Goryunov, I.B. Goryunova, G.V. Bodrin, A.A. Semenov, V.K. Brel, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 9, pp. 1551–1557.

To the 85th Anniversary of birthday of late Yu.G. Gololobov

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Safiulina, A.M., Matveeva, A.G., Evtushenko, A.V. et al. Recovery of lanthanides from digested phosphogypsum solutions using a new organophosphorus extractant, 5-(diphenylphosphoryl)hexan-3-one. Russ J Gen Chem 85, 2128–2134 (2015). https://doi.org/10.1134/S1070363215090170

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363215090170

Keywords

Search

Navigation