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Study of the Metal Exchange Reaction of Cadmium(II) 5,15-Dinitro-2,3,7,8,12,13,17,18-octaethylporphyrinate with d-Metal Salts in Organic Solvents

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Abstract

The kinetics of the metal exchange reactions of cadmium(II) 5,15-dinitro-2,3,7,8,12,13,17,18-octaethylporphyrinate with copper(II) and zinc(II) chlorides in DMF and DMSO were investigated by the spectrophotometric method. The kinetic parameters of the metal exchange reaction were determined. A possible stoichiometric reaction mechanism was proposed. The effect of the solvent and solvate salt nature on the rate of the metal exchange reaction was revealed.

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  1. G.A. Krestov Institute of Solutions Chemistry, Russian Academy of Sciences, 153045, Ivanovo, Russia

    S. V. Zvezdina, N. V. Chizhova & N. Z. Mamardashvili

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  1. S. V. Zvezdina
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  2. N. V. Chizhova
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  3. N. Z. Mamardashvili
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Zvezdina, S.V., Chizhova, N.V. & Mamardashvili, N.Z. Study of the Metal Exchange Reaction of Cadmium(II) 5,15-Dinitro-2,3,7,8,12,13,17,18-octaethylporphyrinate with d-Metal Salts in Organic Solvents. Russ J Gen Chem 92, 256–260 (2022). https://doi.org/10.1134/S1070363222020153

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