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A New [δ-PMoVMoVI11O40]-Based Hybrid as Multifunctional Fluorescent Sensor for Detecting Cations, Anions, and Antibiotics in Aqueous Solution

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Abstract

A new POM-based hybrid, [δ-H4PMoVMoVI11O40](L)5·5H2O (L = 4-methylpyridine-4-yl-1,8-naphthalene dicarboxylamide), was synthesized under hydrothermal conditions and characterized by IR spectroscopy, powder X-ray diffraction, and X-ray photoelectron spectroscopy. This hybrid can acts as multifunctional fluorescent sensor to detect metal cation (Fe3+), anions (Cr2O72– and CrO42–), and antibiotics (NFT = nitrofurantoin, NIT = nitrofurazone, OXY = oxytetracycline) in aqueous environment. The detection limits of the POM-based hybrid were 8.9×10–5, 2.1×10–4, 2.2×10–4, 1.4×10–4, 6.9×10–4, and 6.1×10–4 mol/L for Fe3+, Cr2O72–, CrO42–, NIT, NFT, and OXY, respectively. Furthermore, the quenching mechanism between the POM-based hybrid and the different analytes can be regarded as energy competitive absorption.

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REFERENCES

  1. Ahmadijokani, F. and Tajahmadi, S., Chemosphere, 2021, vol. 264, p. 128466. https://doi.org/10.1016/j.chemosphere.2020.128466

  2. Okoro, H.K., Ayika, S.O., and Ngila, J.C., Appl. Water. Sci., 2018, vol. 8, p. 169. https://doi.org/10.1007/s13201-018-0818-3

  3. Zhu, K., Fan, R.Q., and Wang, P., J. Mater. Chem. (C), 2019, vol. 7, p. 15057. https://doi.org/10.1039/C9TC04700J

  4. Liu, X., Liu, B., Li, G., and Liu, Y.L., J. Mater. Chem. (A), 2018, vol. 6, p. 17177 https://doi.org/10.1039/C8TA03807D

  5. Hou, L.L., Song, Y.H., Wang, L., Xiao, Y.J., and Wu, R., Microchem. J., 2019, vol. 150, p. 104154. https://doi.org/10.1016/j.microc.2019.104154

  6. Shiravand, G., Ghasemi, J.B., Badiei, A., and Ziarani, G.M., J. Photoch. Photobiol. (A), 2019, vol. 389, p. 112261. https://doi.org/10.1016/j.jphotochem.2019.112261

    Article  CAS  Google Scholar 

  7. Suryawanshi, S.B., Mahajan, P.G., Bhopate, D.P., Kolekar, G.B., Patil, S.R., and Bodake, A.J., J. Photoch. Photobiol. (A), 2016, vol. 329, p. 255. https://doi.org/10.1016/j.jphotochem.2016.06.009

    Article  CAS  Google Scholar 

  8. Jone Celestina, J.,Tharmaraj, P., Sheela, C.D., Alphonse, L., and Shakina, J., Opt. Mater., 2020, vol. 109, p. 110444. https://doi.org/10.1016/j.optmat.2020.110444

    Article  CAS  Google Scholar 

  9. Zhou, Z.D., Li, S.Q., Liu, Y., Du, B., Shen, Y.Y., and Wang, C.C., RSC Adv., 2022, vol. 12, 7780. https://doi.org/10.1039/D2RA00376G

  10. Zhou, Z.D., Wang, C.Y., Zhu, G.S., and Wang, C.C., J. Mol. Struct., 2022, vol. 1251, p. 132009. https://doi.org/10.1016/j.molstruc.2021.132009

  11. Dey, C.J., Clust. Sci., 2022, vol. 33, p. 1839. https://doi.org/10.1007/s10876-021-02110-8

    Article  CAS  Google Scholar 

  12. Patel, A. and Sadasivan R., Prog. Mater. Sci., 2020, vol. 118, p. 100759. https://doi.org/10.1016/j.pmatsci.2020.100759

    Article  CAS  Google Scholar 

  13. Luo, X.M., Li, N.F., and Hu, Z.B., Inorg. Chem., 2019, vol. 58, p. 2463. https://doi.org/10.1021/acs.inorgchem.8b03021

    Article  CAS  Google Scholar 

  14. Gumerova, N.I., Roller, A., Giester, G., Krzystek, J., Cano, J., and Rompel, A., J. Am. Chem. Soc., 2022, vol. 142, p. 3336. https://doi.org/10.1021/jacs.9b12797

  15. Liu, L., Zhang, H.Y., Wang, H.J., Chen, S., Wang, J.H., and Sun, J.W., Eur. J. Inorg. Chem., 2019, vol. 13, p. 1839. https://doi.org/10.1002/ejic.201900086

    Article  CAS  Google Scholar 

  16. Zhang, Z., Wang, Y.L., Liu, Y., Huang, S.L., and Yang, G.Y., Nanoscale, 2020, vol. 12, p. 18333. https://doi.org/10.1039/D0NR02945A

    Article  CAS  Google Scholar 

  17. Zhang, Z., Li, H.L., Wang, Y.L., and Yang, G.Y., Inorg. Chem., 2019, vol. 58, p. 2372. https://doi.org/10.1021/acs.inorgchem.8b02805

    Article  CAS  Google Scholar 

  18. Zhang, Z., Wang, Y.L., Li, H.L., Sun, K.N., and Yang, G.Y., CrystEngComm, 2019, vol. 21, p. 2641. https://doi.org/10.1039/C9CE00194H

    Article  CAS  Google Scholar 

  19. Liu, J.X., Zhang, X.B., Li, Y.L., Huang, S.L., and Yang, G.Y., Coord. Chem. Rev., 2020, vol. 414, p. 213260. https://doi.org/10.1016/j.ccr.2020.213260

    Article  CAS  Google Scholar 

  20. Rui, G., Li, X.X., and Zheng, S.T., Coord. Chem. Rev., 2021, vol. 435, p. 213787. https://doi.org/10.1016/j.ccr.2021.213787

    Article  CAS  Google Scholar 

  21. Zhu, Z.K., Lin, Y.Y., Yu, H., Li, X.X., and Zheng, S.T., Angew. Chem. Int. Ed., 2019, vol. 58, p. 16864. https://doi.org/10.1002/anie.201910477

    Article  CAS  Google Scholar 

  22. Jin, L., Zhu, Z.K., Wu, Y.L., Li, X.X., Qi, Y.J., and Zheng, S.T., Angew. Chem. Int. Ed., 2017, vol. 56, p. 16288. https://doi.org/10.1002/anie.201709565

    Article  CAS  Google Scholar 

  23. Liu, J.C., Wang, J.F., Han, Q., Ping, S.G., Liu, L.L., Chen, L.J., Zhao, J.W., Streb, C., and Song, Y.F., Angew. Chem. Int. Ed., 2021, vol. 20, p. 11153. https://doi.org/10.1002/anie.202017318

    Article  CAS  Google Scholar 

  24. Liu, J.C., Han, Q., Chen, L.J., Zhao, J.W., Streb, C., and Song, Y.F., Angew. Chem. Int. Ed., 2018, vol. 28, p. 8416. https://doi.org/10.1002/anie.201882861

    Article  Google Scholar 

  25. Li, R.Y., Li, Y.J., and Lu, X.H., Russ. J. Coord. Chem., 2020, vol. 46, p. 64. https://doi.org/10.1134/S1070328420010042

  26. Uvarova, M.A. and Nefedov, S.E., Russ. J. Inorg. Chem., 2021, vol. 66, p. 839. https://doi.org/10.1134/S0036023621060206

    Article  CAS  Google Scholar 

  27. Zuo, M.H., Zhou, J., and Yu, J., Russ. J. Inorg. Chem., 2021, vol. 66, p. 982. https://doi.org/10.1134/S0036023621070159

    Article  Google Scholar 

  28. Uvarova, M.A. and Nefedov, S.E., Russ. J. Inorg. Chem., 2021, vol. 66, p. 1837. https://doi.org/10.1134/S0036023621120202

    Article  CAS  Google Scholar 

  29. Li, Y.P., Li, G.L., Xin, L.Y., Russ. J. Gen. Chem., 2021, vol. 91, p. 1397. doi 10.1134/S1070363221070197

    Article  CAS  Google Scholar 

  30. Wang, Y.F., Zhang, S.Q., and Feng, Y.X., Russ. J. Gen. Chem., 2021, vol. 91, p. 1566. https://doi.org/10.1134/S1070363221080193

    Article  CAS  Google Scholar 

  31. Chen, X., Yin, P., Guan, L., Russ. J. Gen. Chem., 2021, vol. 91, p. 1584. https://doi.org/10.1134/S1070363221080223

    Article  CAS  Google Scholar 

  32. Wang, X., Li, H., Lin, J.F., Inorg. Chem., 2021, vol. 60, p. 19287. https://doi.org/10.1021/acs.inorgchem.1c03097

  33. Song, X.X., Fu, H.F., Wang, P., Li, H.Y., Zhang, Y.Q., and Wang, C.C., J. Colloid. Interf. Sci., 2018, vol. 532, p. 598. https://doi.org/10.1016/j.jcis.2018.08.029

    Article  CAS  Google Scholar 

  34. Wang, D., Li, Y., and Zhao, J.W., Inorg. Chem., 2020, vol. 59, p. 6839. https://doi.org/10.1021/acs.inorgchem.0c00223

    Article  CAS  Google Scholar 

  35. Wang, Y.L., Ma, Y.Y., Zhao, Q., Hou, L., and Han, Z.G., Sensors Actuators (B), 2020, vol. 305, p. 127469. https://doi.org/10.1016/j.snb.2019.127469

    Article  CAS  Google Scholar 

  36. Wu, H.C., Chen, H.H., Fu, M.H., Li, R., and Niu, J.Y., Dyes Pigm., 2019, vol. 171, p. 107696. https://doi.org/10.1016/j.dyepig.2019.107696

    Article  CAS  Google Scholar 

  37. Brese, N.E. and Okeeffe, M., Acta Crystallogr. (B), 1991, vol. 47, p. 192. https://doi.org/10.1021/ic00071a023

    Article  Google Scholar 

  38. Li, J., Zheng, H.Y., and Su, Z.M., Inorg. Chem. Commun., 2021, vol. 60, p. 1624. https://doi.org/10.1021/acs.inorgchem.0c03110

    Article  CAS  Google Scholar 

  39. Yang, L., Zhang, Z., Xu, N., Liu, Q.Q., and Wang, X.L., Inorg. Chem. Commun., 2021, vol. 132, p. 108819. https://doi.org/10.1016/j.inoche.2021.108819

    Article  CAS  Google Scholar 

  40. Yang, J., Dai, Y., Zhu, X., Wang, Z., Li, Y., Zhuang, Q., Shi, J., and Gu, J., J. Mater. Chem. (A), 2015, vol. 3, p. 7445. https://doi.org/10.1039/C5TA00077G

    Article  CAS  Google Scholar 

  41. Li, Y.W., Li, J., Wan, X.Y., Sheng, D.F., Yan, H., Zhang, S.S., Ma, H.Y., Wang, S.N., Li, D.C., Gao, Z.Y., Dou, J.M., and Sun, D., Inorg. Chem., 2021, vol. 60, p. 671. https://doi.org/10.1021/acs.inorgchem.0c02629

    Article  CAS  Google Scholar 

  42. Chi, J., Zhong, B.Q., Li, Y., Shao, P.P., Liu, G.C., Gao, Q., and Chen, B.K., Z. anorg. allg. Chem., 2021, vol. 647, p. 1284. https://doi.org/10.1002/zaac.202100049

    Article  CAS  Google Scholar 

  43. Kan, W.Q. and Wen, S.Z., Dyes Pigm., 2017, vol. 139, p. 372. https://doi.org/10.1016/j.dyepig.2016.12.039

    Article  CAS  Google Scholar 

  44. Tang, S., Gao, Y., Han, S.W., Chi, J., Zhang, Z., and Liu, G.C., Polyhedron, 2022, vol. 223, p. 115944. https://doi.org/10.1016/j.poly.2022.115944

    Article  CAS  Google Scholar 

  45. Guo, X.R., Yue, G.Q., Huang, J.Z., Liu, C., Zeng, Q., and Wang, L.S., ACS Appl. Mater. Inter., 2018, vol. 10, p. 26118. https://doi.org/10.1021/acsami.8b10529

    Article  CAS  Google Scholar 

  46. Liu, G.C., Li, Y., Chi, J., Xu, N., Wang, X.L., Lin, H.Y., and Chen, Y.Q., Dyes Pigm., 2020, vol. 174, p. 108064. https://doi.org/10.1016/j.dyepig.2019.108064

    Article  CAS  Google Scholar 

  47. Zhang, Q.Q., Ying, G.G., Pan, C.G., Liu, Y.S., and Zhao, J.L., Environ. Sci. Technol., 2015, vol. 49, p. 6772. https://doi.org/10.1021/acs.est.5b00729

    Article  CAS  Google Scholar 

  48. Liu, X.Y., Liu, B., Li, G.H., and Liu, Y.L., J. Mater. Chem. (A), 2018, vol. 6, p. 17177. https://doi.org/10.1039/C8TA03807D

    Article  CAS  Google Scholar 

  49. Bougnom, B.P., and Piddock, L.J.V., Environ. Sci. Technol., 2017, vol. 51, p. 5863. https://doi.org/10.1021/acs.est.7b01852

    Article  CAS  Google Scholar 

  50. Su, C.H. and Guo, F., Inorg. Chem. Commun., 2021, vol. 125, p. 108427. https://doi.org/10.1016/j.inoche.2020.108427

    Article  CAS  Google Scholar 

  51. Han, L.J., Kong, Y.J., Hou, G.Z., Chen, H.C., Zhang, X.M., and Zheng, H.G., Inorg. Chem., 2020, vol. 59, p. 7181. https://doi.org/10.1021/acs.inorgchem.0c00620

    Article  CAS  Google Scholar 

  52. Kang, X.M., Fan, X.Y., Hao, P.Y., Wang, W.M., and Zhao, B., Inorg. Chem., 2019, vol. 2, p. 627. https://doi.org/10.1039/C8QI01260

    Article  Google Scholar 

  53. Sarkar, M. and Biradha, K., Cryst. Growth Des., 2006, vol. 6, p. 202. https://doi.org/10.1021/cg050292l

    Article  CAS  Google Scholar 

  54. Sheldrick, G.M., Acta Crystallogr. (A), 1984, p. C440. https://doi.org/10.1107/S010876738408702X

  55. Zhang, Z., Zhao, J.W., and Yang, G.Y., Eur. J. Inorg. |Chem., 2017, p. 3244. https://doi.org/10.1002/ejic.201700410

  56. Bannani, F., Floquet, S., Leclerc-Laronze, N., Haouas, M., Taulelle, F., Marrot, J., Köerler, P., and Cadot, E., J. Am. Chem. Soc., 2012, vol. 134, p. 19342. https://doi.org/10.1021/ja309302y

    Article  CAS  Google Scholar 

  57. Kalinina, I.V., Peresypkina, E.V., Izarova, N.V., Nkala, F.M., Kortz, U., Kompankov, N.B., and Sokolov, M.N., Inorg. Chem., 2014, vol. 53, p. 2076. https://doi.org/10.1021/ic402668v

    Article  CAS  Google Scholar 

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Funding

This work was supported by the NSFC (no. 21901018, 21971024, 21671025), the Natural Science Foundations and Education Department of Liaoning province (2022-MS-373, 2021-MS-312, LJ2020008), and the Liao Ning Revitalization Talents Program (XLYC1902011).

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  1. Professional Technology Innovation Center of Liaoning Province for Conversion Materials of Solar Cell, College of Chemistry and Materials Engineering, Bohai University, 121013, Jinzhou, China

    S. Li, J.-Y. Sun, Z. Zhang, L. Yang, G.-C. Liu & X.-L. Wang

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  1. S. Li
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  2. J.-Y. Sun
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  3. Z. Zhang
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  4. L. Yang
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Correspondence to Z. Zhang, G.-C. Liu or X.-L. Wang.

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Li, S., Sun, JY., Zhang, Z. et al. A New [δ-PMoVMoVI11O40]-Based Hybrid as Multifunctional Fluorescent Sensor for Detecting Cations, Anions, and Antibiotics in Aqueous Solution. Russ J Gen Chem 92, 2755–2762 (2022). https://doi.org/10.1134/S1070363222120258

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