Abstract
Copolymerization of acrylic acid with new acrylamide biuret derivatives obtained was investigated. Reactivity ratios r 1 and r 2 of these monomers with acrylic acid were calculated. It was found that monomers of mono- and diacrylamide biuret derivatives are of cyclic structures and this fact specifically affects their activity in the copolymerization with acrylic acid.
Similar content being viewed by others
References
Galstyan, G.G., Karamyan, R.A., and Eritsyan, M.L., Polym. Sci., 2003, vol. 45B, no. 7, pp. 190–191.
Doseva, V.N., Shchenkev, S.D., Brochkov, Kh.N., et al., Polym. Sci., 2002, vol. 44B, no. 8, pp. 220–224.
Akopyan, G.V., Karamyan, R.A., Engibaryan, R.N., and Eritsyan, M.L., Russ. J. Appl. Chem., 2007, vol. 80, no. 6, pp. 999–1001.
Barsegyan, Zh.B., Karamyan, R.A., Akopyan, G.V., et al., Russ. J. Appl. Chem., 2010, vol. 83, no. 11, pp. 2024–2027. 5. RF Patent 2122438, 1998.
Sirekanyan, I.N., Safaryan, E.P., Gevorkyan, S.S., and Eritsyan, M.L., Khim. Zh. Armenii, 2007, vol. 60, no. 3, pp. 486–491.
Roth, R.W. and Church, R.F., J. Polym. Sci., 1961, vol. 41, p. 55.
Bagdasar’yan, Kh.S., Teoriya radikal’noi polimerizatsii (Theory of Radical Polymerization), Moscow: Nauka, 1966.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © I.N. Sirekanyan, A.V. Kalantaryan, G.V. Akopyan, M.L. Eripyan, 2014, published in Zhurnal Prikladnoi Khimii, 2014, Vol. 87, No. 10, pp. 1526–1530.
Rights and permissions
About this article
Cite this article
Sirekanyan, I.N., Kalantaryan, A.V., Akopyan, G.V. et al. Copolymerization of acrylic acid with acrylamide biuret derivatives. Russ J Appl Chem 87, 1570–1574 (2014). https://doi.org/10.1134/S1070427214100267
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427214100267