Abstract
Dehydration of molten B2O3 has been studied using electron reflection spectroscopy. Spectral regions of absorption and reflection for groups BO4, BO3OH, and B3O3O3/2OH have been established. It has been shown that dehydration of molten B2O3 leads to a decrease in the concentration of boron four-coordinated groups containing hydroxyl ions in their coordination sphere.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Arbuzov, V.I., Osnovy radiatsionnogo opticheskogo materialovedeniya (Fundamentals of the Radiation Optical Materials Science), St. Petersburg: St. Petersburg National Research University of Informational Technologies, Mechanics, and Optics, 2008 [in Russian].
Von Feltz, A., Amorphe und glasartige anorganische Festkönper, Berlin: Akademie, 1983. Translated under the title Amorfnye i stekloobraznye neorganicheskie tverdye tela, Moscow: Mir, 1986.
Appen, A.A., Khimiya Stekla (The Chemistry of Glass), Leningrad: Khimiya, 1974 [in Russian].
Osipova, L.M., Osipov, A.A., and Bykov, V.N., Structure of High-Alkali Melts in the Lithium Borate System from Vibrational Spectroscopic Data, Glass Phys. Chem., 2007, vol. 33, no. 5, pp. 486–491.
Sinclair, R.N., Desa, J.A., Etherington, G.J., Jonson, P.A., and Wright, A., Neutron Diffraction Studies of Amorphous Solids, J. Non-Cryst. Solids, 1980, vol. 42, nos. 1–3, pp. 107–115.
Johnson, P.A.V., Wright, A.C., and Sinclair, R.N., A Neutron Diffraction Investigation of the Structure of Vitreous Boron Trioxide, J. Non-Cryst. Solids, 1982, vol. 50, no. 3, pp. 281–311.
Mozzi, R.L. and Warren, B.E., The Structure of Vitreous Boron Oxide, J. Appl. Crystallogr., 1970, vol. 3, no. 4, pp. 251–257.
Jellison, G.E., Panek, L.W., Bray, P.J., and Rouse, G.B., Determination of Structure and Bonding in Vitreous B2O3 by Means of 10B, 11B, and 17O NMR, J. Chem. Phys., 1977, vol. 66, no. 2, pp. 802–812.
Goubeau, J. and Keller, H., Raman-Spektren und Struktur von Boroxol-Verbindungen, Z. Anorg. Allg. Chem., 1953, vol. 272, nos. 5–6, pp. 303–312.
Hannon, A.C., Sinclair, R.N., Blackman, J.A., Wright, A.C., and Galeener, F.L., Phonon Spectra of Vitreous B2O3, J. Non-Cryst. Solids, 1988, vol. 106, pp. 116–119.
Walrafen, G.E., Samanta, S.R., and Krishnau, P.N., Raman Investigation of Vitreous and Molten Boric Oxide, J. Chem. Phys., 1980, vol. 72, no. 1, pp. 113–120.
Krogh-Moe, J., Interpretation of the Infra-Red Spectra of Boron Oxide and Alkali Borate Glasses, Phys. Chem. Glasses, 1965, vol. 6, no. 2, pp. 46–54.
Wright, A.C., Sinclair, R.N., Crimley, D.I., Hulme, R.A., Vedishcheva, N.M., Shakhmatkin, B.A., Hannon, A.C., Feller, S.A., Meyer, B.M., Royle, M.L., and Wilkerson, D.L., Borate Glasses, Superstructural Units, and the Random Network Theory, Glass Phys. Chem., 1996, vol. 22, no. 4, pp. 268–278.
Dolin, S.P. and Dyatkina, M.E., Electronic Structure of the Oxides and Oxyanions of Nontransition Elements: Part I. SO2, PO 3−4 , SO 2−4 , and ClO −4 , J. Struct. Chem., 1972, vol. 13, no. 5, pp. 838–843.
Stolper, E.M., The Specification of Water in Silicate Melts, Geochim. Cosmochim. Acta, 1982, vol. 46, no. 12, pp. 2609–2620.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.A. Khokhryakov, A.S. Paivin, S.I. Noritsyn, 2012, published in Fizika i Khimiya Stekla.
Rights and permissions
About this article
Cite this article
Khokhryakov, A.A., Paivin, A.S. & Noritsyn, S.I. Investigation of dehydration of B2O3 at high temperatures using electron spectroscopy technique. Glass Phys Chem 38, 392–395 (2012). https://doi.org/10.1134/S1087659612040074
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1087659612040074