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Dielectric properties of silver-doped nanoporous silicate glasses in the temperature range between –50 and +250°C

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Abstract

The results of measuring dielectric parameters of nanoporous silicate glasses with a nanopore size of 3.5 and 25.7 nm, either doped with silver or not, in the temperature range between–50 and +250°C and the frequency range of 0.1–106 Hz are reported. It is demonstrated that when silver nanoparticles are formed in glass pores, some silver remains in the form of subnanosized molecular clusters Ag n and molecular complexes Ag n –(OH) m . The key dielectric properties of the relaxation centers are determined for different temperature ranges.

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Authors and Affiliations

  1. St. Petersburg National Research University of Information Technologies, Mechanics, and Optics, St. Petersburg, 199034, Russia

    K. S. Zyryanova, A. S. Pshenova & A. I. Sidorov

  2. Herzen State Pedagogical University of Russia, St. Petersburg, 191186, Russia

    R. A. Kastro

  3. St. Petersburg State Electrotechnical University “LETI”, St. Petersburg, 197022, Russia

    A. I. Sidorov

  4. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, St. Petersburg, 199034, Russia

    T. V. Antropova

Authors
  1. K. S. Zyryanova
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  2. R. A. Kastro
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  3. A. S. Pshenova
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  4. A. I. Sidorov
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  5. T. V. Antropova
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Correspondence to A. I. Sidorov.

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Original Russian Text © K.S. Zyryanova, R.A. Kastro, A.S. Pshenova, A.I. Sidorov, T.V. Antropova, 2017, published in Fizika i Khimiya Stekla.

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Zyryanova, K.S., Kastro, R.A., Pshenova, A.S. et al. Dielectric properties of silver-doped nanoporous silicate glasses in the temperature range between –50 and +250°C. Glass Phys Chem 43, 207–214 (2017). https://doi.org/10.1134/S1087659617030142

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  • DOI: https://doi.org/10.1134/S1087659617030142

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