Abstract
In this study, the inhibitive performance of novel synthesised water-soluble of different molecular weight diblock copolymers of derivative methyl methacrylate (VB84, VB206, VB207, VB361, VB371,VB406) on the corrosion behavior of AISI 304 stainless steel in 10–3 M HCl containing various concentrations of polymers was investigated using potentiodynamic polarisation, electrochemical impedance spectroscopy (EIS), scanning electron microscopy(SEM), energy dispersive X-ray analysis (EDX), atomic force microscopy (AFM) and inductively coupled plasma optical emmision spectrometry (ICP-OES) methods. Polarisation curves indicated that all studied polymers were acting as mixed type inhibitors. All electrochemical measurements showed that inhibition efficiencies increased with increasing polymer concentration. It was determined that the increase of inhibitor efficiency by concentration resulted from the adsorption of polymers to metal surface, and the adsorption fitted to the Langmuir adsorption equation. The variation in inhibitive efficiency mainly depends on the type and the nature of the substituents present in the polymer molecule and also depends on the molecular weight of the polymer. The best inhibition in 10-3 M HCl shows VB84 homopolymer. Surface images obtained with SEM, EDX, and AFM methods determined by verifying these results that inhibitors decrease the dissolution of metal, prevented the corrosion.
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REFERENCES
Bütün, V., Lowe, A.B., Billingham, N.C., and Armes, S.P., J. Am. Chem. Soc., 1999, vol. 121, p. 4288.
Bütün, V., Vamvakaki, M., Billingham, N.C., and Armes, S.P., Polymer, 2000, vol. 41, p. 3173.
Bütün, V, Armes, S.P., and Billingham, N.C., Polymer, 2001, vol. 42, p. 5993.
Bütün, V., Bennett, C.E., Vamvakaki, M., Lowe, A.B., Billingham, N.C., and Armes, S.P., J. Mater. Chem., 1997, vol. 7, p. 1693.
Vamvakaki, M., Unali, G.F., Bütün, V., Boucher, S., Robinson, K.L., Billingham, N.C., and Armes, S.P., Macromolecules, 2001, vol. 34, p. 1639.
Bütün, V., Polymer, 2003, vol. 44, p. 7321.
Bütün, V., Billingham, N.C., and Armes, S.P., Chem. Commun., 1997, vol. 7, p. 671. https://doi.org/10.1039/A700772H
De Paz-Banez, M.V., Robinson, K.L., Bütün, V., and Armes, S.P., Polymer, 2001, vol. 42, p. 29.
Kawauchi, Y., Kouka, A., Guragain, S., Bastakoti, B.P., Yusa, S., and Nakashima, K., Colloids Surf., A, 2013, vol. 434, p. 56.
Gao, C., Liu, M., Chen, S., Jin, S., and Chen, J., Int. J. Pharm., 2009, vol. 371, p. 16.
Hu, J., Zhang, G., Ge, Z., and Liu, S., Prog. Polym. Sci., 2013, vol. 39, p. 1096.
Srimathi, M., Rajalakshmi, R., and Subhashini, S., Arabian J. Chem., 2010. vol. 7, p. 647.
Daoud, D., Douadi, T., Issaadi, S., and Chafaa, S., Corros. Sci., 2014, vol. 79, p. 50.
Azghandi, M.V., Davoodi, A., Farzi, G., and Kosari, A., Corros. Sci., 2012, vol. 64, p. 44.
Farag, A.A. and El-Din, M.R.E., Corros. Sci., 2012, vol. 64, p. 174.
Hegazy, M.A., Badawi, A.M., Abd El Rehim, S.S. and Kamel, W.M., Corros. Sci., 2013, vol. 69, p. 110.
Javadian, S., Yousefi, A., and Neshati, J., Appl. Surf. Sci., 2013, vol. 285, p. 674.
Riggs, O.L., US Patent 3 061 553, 1962.
Al-Sabagh, A.M., Kandile, N.Gh., Nasser, N.M., Mishrif, M.R., and El-Tabey, A.E., Egypt. J. Pet., 2013, vol. 22, pp. 351–365.
Zadeh, A.R.H., Danaee, I., and Maddahy, M.D., J. Mater. Sci. Technol., 2013, vol. 29, no. 9, p. 884.
Zhang, Q., Gao, Z., Xu, F., and Zou, X., Colloids Surf., A, 2011, p. 380, p. 191.
El-Latef, H.M.A., Abbasov, V.M., Aliyeva, L.I., Qasimov, E.E., and Ismayilov, I.T., Mater. Chem. Phys., 2013, vol. 142, p. 502.
Bae, Y.H., Okano, T., and Kim, S.W., J. Polym. Sci., Part B: Polym. Phys., 1990, vol. 28, p. 923.
Luan, C.H., Harris, R.D., Prasad, K.U., and Urry, D.W., Biopolymers, 1990, vol. 29, p. 1699.
Otake, K., Inotamo, H., Konno, M., and Saito, S., Macromolecules, 1990, vol. 23, p. 283.
Feil, H., Bae, Y.H., Feijen, J., and Kim, S.W., Macromolecules, 1993, vol. 26, p. 2496.
Bahrami, M.J., Hosseini, S.M.A., and Pilvar, P., Corros. Sci., 2010, vol. 52, p. 2793.
Liu, B., Xi, H., Li, Z., and Xia, Q., Appl. Surf. Sci., 2012, vol. 258, p. 6679.
Bütün, V., Bennett, C.E., Vamvakaki, M., Lowe, A.B., Billingham, N.C., and Armes, S.P., J. Mater. Chem., 1997, vol. 7, p. 1693.
Karthikaiselvi, R. and Subhashini, S., Arabian J. Chem., 2012. Karthikaiselvi, R. and Subhashini, S., Arabian J. Chem., 2017, vol. 10, no. 1, Suppl., p. S627.https://doi.org/10.1016/j.arabjc.2012.10.024
Amin, M.A., Abd El Rehim, S.S., and Abdel-Fatah, H.T.M., Corros. Sci., 2009, vol. 51, p. 882.
Fouda, A.S. and Ellithy, A.S., Corros. Sci., 2009, vol. 51, p. 868.
Solmaz, R., Altunbaş, E., and Kardaş, G., Mater. Chem. Phys., 2011, vol. 125, p. 796.
Azghandi, M.V., Davoodi, A., Farzi, G., and Kosari, A., Corros. Sci., 2012, vol. 64, p. 44.
Özkır, D., Kayakırılmaz, K., Bayol, E., Gurten, A.A., and Kandemirli, F., Corros. Sci., 2013, vol. 56, p. 143.
Ahamad, I. and Quraishi, M.A., Corros. Sci., 2009, vol. 51, p. 2006.
Desimone, M.P., Gordillo, G., and Simison, S.N., Corros. Sci., 2011, vol. 53, p. 4033.
Allam, N.K., Appl. Surf. Sci., 2007, vol. 253, p. 4570.
Singh, A.K., Shukla, S.K., Quraishi, M.A., and Ebenso, E.E., J. Taiwan Inst. Chem. Eng., 2012, vol. 43, p. 463.
Ferreira, E.S., Giacomelli, C., Giacomelli, F.C., and Spinelli, A., Sci. Direct, 2004, vol. 83, p. 129.
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Büyüksağiş, A., Çiçek, H.Y. & Bütün, V. Tertiary Amine Methacrylate based Polymers as Corrosion Inhibitors in HCl Solution. Part II. Prot Met Phys Chem Surf 55, 963–972 (2019). https://doi.org/10.1134/S207020511905006X
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DOI: https://doi.org/10.1134/S207020511905006X