Abstract
The corrosion inhibition and adsorption characteristics of the extract obtained from the plant Papaver somniferum L. (PSL) by electrochemical methods at different temperatures (25, 35 and 45°C) were investigated in 0.2 M HCl and 0.2 M HCl + x ppm PSL solutions on AISI 304 stainles steel (AISI 304 SS), ETIAL 150 aluminum alloy (ETIAL 150 Al) and copper. The best inhibition was obtained containing 0.2 M HCl + 500 ppm PSL inhibitor concentration solutions. Surface observations of metals after standing experiments were investigated by atomic force microscopy (AFM), scanning electron microscopy (SEM) and energy scattering X-ray method EDX). The inhibition effect was increased with an increase in inhibitor concentration. Extract adsorbed on the surface of metals obeyed the Langmuir adsorption isotherm. The Langmuir adsorption isotherms confirm the physical adsorption mechanism and the inhibitor is a mixed type inhibitor. SEM images show cracks and pits on the surfaces in extract free solutions. AFM and SEM were showed thick dense film on metal surfaces in containing extract solutions. The occuring film closed all the active corrosion sites on metals and inhibited corrosion mechanism. Some thermodynamic and kinetic parameters for the adsorption process, that were adsorption equilibrium constant (Kads), Gibbs adsorption free energy (Gads), and activation energy of corrosion reaction (Ea), were calculated and discussed by using Tafel results. Arrhenius energies increased with an increase in inhibitor concentration. Activation energies and Gibbs free energies for the inhibition reactions were supported the physical adsorption mechanism.
Similar content being viewed by others
REFERENCES
Hamdy, A. and El-Gendy, N.S., Egypt.J. Pet., 2013, vol. 22, p. 17.
Jokar, M., Farahani, T.S., and Ramezanzadeh, B., J. Taiwan Inst. Chem. Eng., 2016, vol. 63, p. 436.
Abiola, O.K. and Tobun, Y., Chin. Chem. Lett., 2010, vol. 21, p. 1449.
Anupama, K.K., Ramya, K., Shainy, K.M., and Joseph, A., Mater. Chem. Phys., 2015, vol. 167, p. 28.
Anupama, K.K., Ramya, K. and Joseph, A., J. Mol. Liq., 2016, vol. 216, p. 146.
El Bribri, A., Tabyaoui, M., Tabyaoui, B., El Attari, H., and Bentiss, F., Mater. Chem. Phys., 2013, vol. 141, p. 240.
El-Etre, A.Y., Appl. Surf. Sci., 2006, vol. 252 p. 8521.
Lebrini, M., Robert, F., Lecante, A., and Roos, C., Corros. Sci., 2011, vol. 53, p. 687.
Muthukrishnan, P., Prakash, P., Jeyaprabha, B., and Shankar, K., Arabian J. Chem., 2015. https://doi.org/10.1016/j.arabjc.2015.09.005
Rahal, C., Masmoudi, M., Abdelhedi, R., Sabot, R., Jeannin, M., Bouaziz, M., and Refait, P., J. Electroanal. Chem., 2016, vol. 769, p. 53.
Raja, P.B., Qureshi, A.K., Rahim, A.A., Osman, H., and Awang, K., Corros. Sci., 2013, vol. 69, p. 292.
Rajeswari, V., Kesavan, D., Gopiraman, M., Viswanathamurthi, P., Poonkuzhali, K., and Palvannan, T., Appl. Surf. Sci., 2014, vol. 314, p. 537.
Rose, K., Kim, B.S., Rajagopal, K., Arumugam, S., and Devarayan, K., J. Mol. Liq., 2016, vol. 214, p. 111.
Koç, H., Camcı, H., Kadiroğlu, A., ve Gür, K., Bitkisel Araştırma Dergisi, 2006, vol. 1, p. 31.
Allam, N.K., Appl. Surf. Sci., 2007, vol. 253, p. 4570.
Odob, I.B., Ebenso, E.E., and Kabanda, M.M., J. Environ. Chem. Eng., 2013, vol. 1, p. 431.
Solmaz, R., Altunbaş, E., and Kardaş, G., Mater. Chem. Phys., 2011, vol. 125, p. 796.
Al-Sabagh, A.M., Kandile, N.Gh., Nasser, N.M., Mishrif, M.R., and El-Tabey, A.E., Egypt.J. Pet., 2013, vol. 22, p. 351.
Riggs, O.L., US Patent 3061553, 1962.
Farag, A.A. and El-Din, M.R.E., Corros. Sci., 2012, vol. 64, p. 174.
Zadeh, A.R.H., Danaee, I., and Maddahy, M.D., J. Mater. Sci. Technol., 2013, vol. 29, no. 9, p. 884.
Zhang, Q., Gao, Z., Xu, F., and Zou, X., Colloids Surf., A, 2011, vol. 380, p. 191.
El-Latef, H.M.A., Abbasov, V.M., Aliyeva, L.I., Qasimov, E.E., and Ismayilov, I.T., Mater. Chem. Phys., 2013, vol. 142, p. 502.
Javadian, S., Yousefi, A., and Neshati, J., Appl. Surf. Sci., 2013, vol. 285, p. 674.
Hegazy, M.A., Badawi, A.M., Abd El Rehim, S.S., and Kamel, W.M., Corros. Sci., 2013, vol. 69, p. 110.
Karthikaiselvi, R. and Subhashini, S., Arabian J. Chem., 2012, vol. 10, p. S627. https://doi.org/10.1016/j.arabjc.2012.10.024
Özkır, D., Kayakırılmaz, K., Bayol, E., Gurten, A.A., and Kandemirli, F., Corros. Sci., 2013, vol. 56, p. 143.
Desimone, M.P., Gordillo, G., and Simison, S.N., Corros. Sci., 2011, vol. 53, p. 4033.
Akalezi, C.O. and Oguzie, E.E., Int. J. Ind. Chem., 2016, vol. 7, p. 81.
Singh, A.K., Shukla, S.K., Quraishi, M.A., and Ebenso, E.E., J. Taiwan Inst. Chem. Eng., 2012, vol. 43, p. 463.
Amin, M.A., Abd El Rehim, S.S., and Abdel-Fatah, H.T.M., Corros. Sci., 2009, vol. 51, p. 882.
Fouda, A.S. and Ellithy, A.S., Corros. Sci., 2009, vol. 51, p. 868.
Odewunmi, N.A., Umoren, S.A. and Gasem, Z.M., Ind. Eng. Chem., 2015, vol. 21, p. 239.
Alaneme, K.K., Olusegun, S.J., and Oluwabunkunmi, T.A., AlexandriaEng. J., 2016, vol. 55, no. 1, p. 673.
Alaneme, K.K., Olusegun, S.J., and Alo, A.W., AlexandriaEng. J., 2016, vol. 55, no. 2, p. 1069. https://doi.org/10.1016/j.aej.2016.03.012
Thanapackiam, P., Rameshkumar, S., Subramanian, S.S., and Mallaiya, K., Mater. Chem. Phys., 2016, vol. 174, p. 129.
Bahrami, M.J., Hosseini, S.M.A., and Pilvar, P., Corros. Sci., 2010, vol. 52, p. 2793.
Liu, B., Xi, H., Li, Z., and Xia, Q., Appl. Surf. Sci., 2012, vol. 258, p. 6679.
Azghandi, M.V., Davoodi, A., Farzi, G., and Kosari, A., Corros. Sci., 2012, vol. 64, p. 44.
Srimathi, M., Rajalakshmi, R., and Subhashini, S., Arabian J. Chem., 2010. vol. 7, p. 647.
Atta, A.M., El-Azabawy, O.E., Ismail, H.S., and Hegazy, M.A., Corros. Sci., 2011, vol. 53, p. 1680.
Anupama, K.K., Ramya, K., and Joseph, A., Measurement, 2017, vol. 95, p. 297.
Sivaraju, M. and Kannan, K., Int. J. ChemTech Res., 2010, vol. 2, p. 1243.
Lei, Y., Zhiyong, L., Weibin, Y., and Zixiao, W., Curr. Anal. Chem., 2016, vol. 12, p. 141.
Funding
The authors appreciated Afyon Kocatepe University, Scientific Research Projects Coordinator Unit (project no. 14FENED04).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Aysel Buyuksagis, Meltem Dİlek The Use of papaver somniferum L. Plant Extract as Corrosion Inhibitor. Prot Met Phys Chem Surf 55, 1182–1194 (2019). https://doi.org/10.1134/S2070205119060042
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S2070205119060042