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The Use of papaver somniferum L. Plant Extract as Corrosion Inhibitor

  • PHYSICOCHEMICAL PROBLEMS OF MATERIALS PROTECTION
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Abstract

The corrosion inhibition and adsorption characteristics of the extract obtained from the plant Papaver somniferum L. (PSL) by electrochemical methods at different temperatures (25, 35 and 45°C) were investigated in 0.2 M HCl and 0.2 M HCl + x ppm PSL solutions on AISI 304 stainles steel (AISI 304 SS), ETIAL 150 aluminum alloy (ETIAL 150 Al) and copper. The best inhibition was obtained containing 0.2 M HCl + 500 ppm PSL inhibitor concentration solutions. Surface observations of metals after standing experiments were investigated by atomic force microscopy (AFM), scanning electron microscopy (SEM) and energy scattering X-ray method EDX). The inhibition effect was increased with an increase in inhibitor concentration. Extract adsorbed on the surface of metals obeyed the Langmuir adsorption isotherm. The Langmuir adsorption isotherms confirm the physical adsorption mechanism and the inhibitor is a mixed type inhibitor. SEM images show cracks and pits on the surfaces in extract free solutions. AFM and SEM were showed thick dense film on metal surfaces in containing extract solutions. The occuring film closed all the active corrosion sites on metals and inhibited corrosion mechanism. Some thermodynamic and kinetic parameters for the adsorption process, that were adsorption equilibrium constant (Kads), Gibbs adsorption free energy (Gads), and activation energy of corrosion reaction (Ea), were calculated and discussed by using Tafel results. Arrhenius energies increased with an increase in inhibitor concentration. Activation energies and Gibbs free energies for the inhibition reactions were supported the physical adsorption mechanism.

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REFERENCES

  1. Hamdy, A. and El-Gendy, N.S., Egypt.J. Pet., 2013, vol. 22, p. 17.

    Google Scholar 

  2. Jokar, M., Farahani, T.S., and Ramezanzadeh, B., J. Taiwan Inst. Chem. Eng., 2016, vol. 63, p. 436.

    Article  CAS  Google Scholar 

  3. Abiola, O.K. and Tobun, Y., Chin. Chem. Lett., 2010, vol. 21, p. 1449.

    Article  CAS  Google Scholar 

  4. Anupama, K.K., Ramya, K., Shainy, K.M., and Joseph, A., Mater. Chem. Phys., 2015, vol. 167, p. 28.

    Article  CAS  Google Scholar 

  5. Anupama, K.K., Ramya, K. and Joseph, A., J. Mol. Liq., 2016, vol. 216, p. 146.

    Article  CAS  Google Scholar 

  6. El Bribri, A., Tabyaoui, M., Tabyaoui, B., El Attari, H., and Bentiss, F., Mater. Chem. Phys., 2013, vol. 141, p. 240.

    Article  CAS  Google Scholar 

  7. El-Etre, A.Y., Appl. Surf. Sci., 2006, vol. 252 p. 8521.

    Article  CAS  Google Scholar 

  8. Lebrini, M., Robert, F., Lecante, A., and Roos, C., Corros. Sci., 2011, vol. 53, p. 687.

    Article  CAS  Google Scholar 

  9. Muthukrishnan, P., Prakash, P., Jeyaprabha, B., and Shankar, K., Arabian J. Chem., 2015. https://doi.org/10.1016/j.arabjc.2015.09.005

  10. Rahal, C., Masmoudi, M., Abdelhedi, R., Sabot, R., Jeannin, M., Bouaziz, M., and Refait, P., J. Electroanal. Chem., 2016, vol. 769, p. 53.

    Article  CAS  Google Scholar 

  11. Raja, P.B., Qureshi, A.K., Rahim, A.A., Osman, H., and Awang, K., Corros. Sci., 2013, vol. 69, p. 292.

    Article  CAS  Google Scholar 

  12. Rajeswari, V., Kesavan, D., Gopiraman, M., Viswanathamurthi, P., Poonkuzhali, K., and Palvannan, T., Appl. Surf. Sci., 2014, vol. 314, p. 537.

    Article  CAS  Google Scholar 

  13. Rose, K., Kim, B.S., Rajagopal, K., Arumugam, S., and Devarayan, K., J. Mol. Liq., 2016, vol. 214, p. 111.

    Article  CAS  Google Scholar 

  14. Koç, H., Camcı, H., Kadiroğlu, A., ve Gür, K., Bitkisel Araştırma Dergisi, 2006, vol. 1, p. 31.

    Google Scholar 

  15. Allam, N.K., Appl. Surf. Sci., 2007, vol. 253, p. 4570.

    Article  CAS  Google Scholar 

  16. Odob, I.B., Ebenso, E.E., and Kabanda, M.M., J. Environ. Chem. Eng., 2013, vol. 1, p. 431.

    Article  Google Scholar 

  17. Solmaz, R., Altunbaş, E., and Kardaş, G., Mater. Chem. Phys., 2011, vol. 125, p. 796.

    Article  CAS  Google Scholar 

  18. Al-Sabagh, A.M., Kandile, N.Gh., Nasser, N.M., Mishrif, M.R., and El-Tabey, A.E., Egypt.J. Pet., 2013, vol. 22, p. 351.

    Google Scholar 

  19. Riggs, O.L., US Patent 3061553, 1962.

  20. Farag, A.A. and El-Din, M.R.E., Corros. Sci., 2012, vol. 64, p. 174.

    Article  CAS  Google Scholar 

  21. Zadeh, A.R.H., Danaee, I., and Maddahy, M.D., J. Mater. Sci. Technol., 2013, vol. 29, no. 9, p. 884.

    Article  CAS  Google Scholar 

  22. Zhang, Q., Gao, Z., Xu, F., and Zou, X., Colloids Surf., A, 2011, vol. 380, p. 191.

    Article  CAS  Google Scholar 

  23. El-Latef, H.M.A., Abbasov, V.M., Aliyeva, L.I., Qasimov, E.E., and Ismayilov, I.T., Mater. Chem. Phys., 2013, vol. 142, p. 502.

    Article  Google Scholar 

  24. Javadian, S., Yousefi, A., and Neshati, J., Appl. Surf. Sci., 2013, vol. 285, p. 674.

    Article  CAS  Google Scholar 

  25. Hegazy, M.A., Badawi, A.M., Abd El Rehim, S.S., and Kamel, W.M., Corros. Sci., 2013, vol. 69, p. 110.

    Article  CAS  Google Scholar 

  26. Karthikaiselvi, R. and Subhashini, S., Arabian J. Chem., 2012, vol. 10, p. S627. https://doi.org/10.1016/j.arabjc.2012.10.024

    Article  CAS  Google Scholar 

  27. Özkır, D., Kayakırılmaz, K., Bayol, E., Gurten, A.A., and Kandemirli, F., Corros. Sci., 2013, vol. 56, p. 143.

    Article  Google Scholar 

  28. Desimone, M.P., Gordillo, G., and Simison, S.N., Corros. Sci., 2011, vol. 53, p. 4033.

    Article  CAS  Google Scholar 

  29. Akalezi, C.O. and Oguzie, E.E., Int. J. Ind. Chem., 2016, vol. 7, p. 81.

    Article  CAS  Google Scholar 

  30. Singh, A.K., Shukla, S.K., Quraishi, M.A., and Ebenso, E.E., J. Taiwan Inst. Chem. Eng., 2012, vol. 43, p. 463.

    Article  CAS  Google Scholar 

  31. Amin, M.A., Abd El Rehim, S.S., and Abdel-Fatah, H.T.M., Corros. Sci., 2009, vol. 51, p. 882.

    Article  CAS  Google Scholar 

  32. Fouda, A.S. and Ellithy, A.S., Corros. Sci., 2009, vol. 51, p. 868.

    Article  CAS  Google Scholar 

  33. Odewunmi, N.A., Umoren, S.A. and Gasem, Z.M., Ind. Eng. Chem., 2015, vol. 21, p. 239.

    Article  CAS  Google Scholar 

  34. Alaneme, K.K., Olusegun, S.J., and Oluwabunkunmi, T.A., AlexandriaEng. J., 2016, vol. 55, no. 1, p. 673.

    Google Scholar 

  35. Alaneme, K.K., Olusegun, S.J., and Alo, A.W., AlexandriaEng. J., 2016, vol. 55, no. 2, p. 1069. https://doi.org/10.1016/j.aej.2016.03.012

    Article  Google Scholar 

  36. Thanapackiam, P., Rameshkumar, S., Subramanian, S.S., and Mallaiya, K., Mater. Chem. Phys., 2016, vol. 174, p. 129.

    Article  CAS  Google Scholar 

  37. Bahrami, M.J., Hosseini, S.M.A., and Pilvar, P., Corros. Sci., 2010, vol. 52, p. 2793.

    Article  CAS  Google Scholar 

  38. Liu, B., Xi, H., Li, Z., and Xia, Q., Appl. Surf. Sci., 2012, vol. 258, p. 6679.

    Article  CAS  Google Scholar 

  39. Azghandi, M.V., Davoodi, A., Farzi, G., and Kosari, A., Corros. Sci., 2012, vol. 64, p. 44.

    Article  Google Scholar 

  40. Srimathi, M., Rajalakshmi, R., and Subhashini, S., Arabian J. Chem., 2010. vol. 7, p. 647.

    Article  Google Scholar 

  41. Atta, A.M., El-Azabawy, O.E., Ismail, H.S., and Hegazy, M.A., Corros. Sci., 2011, vol. 53, p. 1680.

    Article  CAS  Google Scholar 

  42. Anupama, K.K., Ramya, K., and Joseph, A., Measurement, 2017, vol. 95, p. 297.

    Article  Google Scholar 

  43. Sivaraju, M. and Kannan, K., Int. J. ChemTech Res., 2010, vol. 2, p. 1243.

    Google Scholar 

  44. Lei, Y., Zhiyong, L., Weibin, Y., and Zixiao, W., Curr. Anal. Chem., 2016, vol. 12, p. 141.

    Article  Google Scholar 

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Funding

The authors appreciated Afyon Kocatepe University, Scientific Research Projects Coordinator Unit (project no. 14FENED04).

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Correspondence to Aysel Buyuksagis.

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Aysel Buyuksagis, Meltem Dİlek The Use of papaver somniferum L. Plant Extract as Corrosion Inhibitor. Prot Met Phys Chem Surf 55, 1182–1194 (2019). https://doi.org/10.1134/S2070205119060042

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