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Thermodynamic Properties of a Hyperbranched Pyridylphenylene Polymer with a Phenylene Bridging Group

  • HEAT CAPACITY: EXPERIMENTS AND CALCULATIONS
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Abstract

Precision adiabatic vacuum calorimetry and differential scanning calorimetry in the range of 6–650 K are used to study the temperature dependence of the heat capacity of a hyperbranched pyridylphenylene polymer with a phenylene bridging group. An anomalous change in the heat capacity (a glassy G transition) is revealed in the low-temperature range of 10–18 K. The heat capacity curve displays an exothermic effect starting from T = 400 K, due to the crosslinking of hyperbranched polymer macromolecules. The obtained experimental data are used to calculate the polymer’s standard thermodynamic functions for the range of T → 0 to 400 K, along with the standard entropy of its formation at T = 298.15 K.

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Funding

This work was supported by the RF Ministry of Science and Higher Education, project no. 0729-2020-0039; the Priority 2030 Strategic Academic Leadership Program, project N-489-99_2021-2022; and RF Presidential Grant for Young Scientists and Graduate Students no. SP-1369.2022.4.

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Authors and Affiliations

  1. Lobachevsky State University, 603105, Nizhny Novgorod, Russia

    A. V. Markin, N. N. Smirnova & S. S. Sologubov

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    E. S. Chamkina, N. V. Kuchkina & Z. B. Shifrina

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  1. A. V. Markin
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  2. N. N. Smirnova
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  3. S. S. Sologubov
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  4. E. S. Chamkina
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  5. N. V. Kuchkina
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  6. Z. B. Shifrina
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Correspondence to A. V. Markin.

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Translated by E. Domoroshchina

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Markin, A.V., Smirnova, N.N., Sologubov, S.S. et al. Thermodynamic Properties of a Hyperbranched Pyridylphenylene Polymer with a Phenylene Bridging Group. Russ. J. Phys. Chem. 96, 1888–1894 (2022). https://doi.org/10.1134/S0036024422090230

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  • DOI: https://doi.org/10.1134/S0036024422090230

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