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On the Relationship between Heat Exchanges and Temperature of Bodies at Thermal Equilibrium

  • CHEMICAL THERMODYNAMICS AND THERMOCHEMISTRY
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Abstract

The paper refers first to the definition of heat prevalent in thermodynamics. The problem of the temperature and of the exchanges of heat in the bodies at thermal equilibrium is then addressed, providing a new point of view based on the principle of mobile equilibrium.

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Fig. 1.
Fig. 2.

Notes

  1. The value has been calculated from \({{{v}}_{s}} = 2a{{{v}}_{{\text{E}}}}\) where \({{{v}}_{{\text{E}}}} = k{{\theta }_{{\text{E}}}}{\text{/}}h = 5.087 \times {{10}^{{12}}}\) s–1 and \(a = 3.615 \times {{10}^{{ - 10}}}\) m is the lattice parameter at 298.15 K.

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ACKNOWLEDGMENTS

Thanks are due to colleagues Paolo Maria Ossi, Gabriele Salvago and Caterina Ducati for reading and commenting the text. The paper is dedicated to Umberto Ducati (1942–2021) who introduced me to the science of thermodynamics.

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This research was carried out without financial support.

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Bestetti, M. On the Relationship between Heat Exchanges and Temperature of Bodies at Thermal Equilibrium. Russ. J. Phys. Chem. 97, 1108–1112 (2023). https://doi.org/10.1134/S0036024423060183

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  • DOI: https://doi.org/10.1134/S0036024423060183

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