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Polarographic and Voltammetric Investigation of Heterocyclic Monoazo Compounds Azodicarboxylic Dimorpholide and 1,1'-Azodicarbonyl Dipiperidine

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Abstract

The electrochemical behaviours of azodicarboxylic dimorpholide (ADM) and 1,1′-azodicarbonyl dipiperidine (ADP) have been investigated in Britton–Robinson (B–R) buffer solutions over a wide pH range (2.0–12.0) by means of some voltammetric and polarographic techniques. During the cathodic potential scan of ADM and ADP, a major signal for the reduction of –N=N– moiety was obtained. The effects of pH and scan rate on the cathodic signal were also studied. On the basis of voltammetric and polarographic data, an overall mechanism for the electrochemical reduction process of –N=N– moiety on both ADM and ADP molecules was postulated and discussed.

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ACKNOWLEDGMENTS

This manuscript was produced from PhD Thesis of the first author and supervised by the second author. Also, this research work was presented in part and in poster form at 10th International Electrochemistry Meeting in Konya, September 4–8, 2013, Abstract Book, pp. 74, 75, Konya, Turkey.

Funding

This study was financially supported by the Scientific Research Foundation of Ondokuz Mayıs University, Turkey (project number: PYO.FEN.1904.12.016).

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  1. Department of Machinery and Metal Technologies, Merzifon Vocational School, Amasya University, 05300, Merzifon, Amasya, Turkey

    Neslihan Özdemir Tanju

  2. Department of Chemistry, Faculty of Science, Ondokuz Mayıs University, 55139, Atakum, Samsun, Turkey

    Ender Biçer

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Neslihan Özdemir Tanju, Ender Biçer Polarographic and Voltammetric Investigation of Heterocyclic Monoazo Compounds Azodicarboxylic Dimorpholide and 1,1'-Azodicarbonyl Dipiperidine. Russ J Electrochem 59, 79–91 (2023). https://doi.org/10.1134/S102319352301010X

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