Skip to main content
Log in

Surface species of the nematic mixture E7 obtained by electrochemical insertion of Li+ ions

  • Tips and Tricks - Soft Matter
  • Published:
The European Physical Journal E Aims and scope Submit manuscript

Abstract

We studied here the influence of Li+ ions on the benzene rings of nematic mixture E7, which is electrochemically adsorbed onto gold electrode surface, to highlight the ability of this mixture for the applications in the field of the rechargeable Li+-ion batteries. Raman spectra support the changes observed in electrochemical analyses while contact angle measurements show that wetting properties of E7 layer were modified after deposition of this mixture onto gold support and the doping with Li+ ions.

Graphical abstract

Contact angle of acetonitrile drops and Raman spectrum of the film of E7 nematic mixture are two main properties which show deep modifications into the film by electro chemical deposition

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Scheme 1
Fig. 5

Similar content being viewed by others

Data availability

No data are associated with the manuscript.

References

  1. G.P. Crawford, R. Stannarius, J.W. Doane, Phys. Rev. A 44, 2558 (1991)

    Article  ADS  Google Scholar 

  2. G.P. Crawford, S. Zumer (eds.), Liquid crystals in complex geometries formed by polymer and porous networks. (Taylor & Francis, London, 1996), p.606

    Google Scholar 

  3. S. Frunza, L. Frunza, C. Ganea, I. Zgura, A.R. Brás, A. Schönhals, Eur. Phys. J. Plus 131, 27 (2016)

    Article  Google Scholar 

  4. S. Frunza, C.P. Ganea, I. Zgura, L. Frunza, A. Schönhals, Liq. Cryst. 47(6), 908 (2020)

    Article  Google Scholar 

  5. Z. Zhong, D.E. Schuele, W. Gordon, K.J. Adamic, R.B. Akins, J. Polymer Sci. Part B Polymer Phys. 30, 1443 (1992)

    Article  ADS  Google Scholar 

  6. M.T. Viciosa, A.M. Nunes, A. Fernandes, P.L. Almeida, M.H. Godinho, M.D. Dionisio, Liq. Cryst. 29(3), 429 (2002)

    Article  Google Scholar 

  7. A. Schönhals, S. Frunza, L. Frunza, T. Unruh, B. Frick, R. Zorn, Eur. Phys. J. Spec. Topics 189, 251 (2010)

    Article  ADS  Google Scholar 

  8. A.R. Brás, S. Frunza, L. Guerreiro, I.M. Fonseca, A. Corma, L. Frunza, M. Dionísio, A. Schönhals, J. Chem. Phys. 132, 224508 (2010)

    Article  ADS  Google Scholar 

  9. H. Park, E.P.J. Parrott, F. Fan, M. Lim, H. Han, V.G. Chigrinov, E. Pickwell-MacPherson, Opt. Express 20(11), 11899 (2020)

    Article  ADS  Google Scholar 

  10. A. Selevou, G. Papamokos, T. Yildirim, H. Duran, M. Steinhart, G. Floudas, RSC Adv. 9, 37846 (2019)

    Article  ADS  Google Scholar 

  11. R. Basu, L.J. Atwood, G.W. Sterling, Crystals 10, 123 (2020). https://doi.org/10.3390/cryst10020123

    Article  Google Scholar 

  12. R. Basu, L.J. Atwood, Opt. Mater. Express 9(3), 1441 (2019)

    Article  ADS  Google Scholar 

  13. C.-J. Hsu, L.-J. Lin, M.-K. Huang, C.-Y. Huang, Crystals 7, 287 (2017). https://doi.org/10.3390/cryst7100287

    Article  Google Scholar 

  14. X. Liu, X. Xia, L. Yang, J. Zhu, M. Xu, G. Zhang, G. Xia, L. Qiu, H. Lu, Liq. Cryst. 48(10), 1357 (2021). https://doi.org/10.1080/02678292.2020.1870009

    Article  Google Scholar 

  15. D. Manaila Maximean, O. Danila, P.L. Almeida, C. Paul Ganea, Beilstein J. Nanotechnol. 9, 155 (2018)

    Article  Google Scholar 

  16. D. Manaila Maximean, O. Danila, C. Paul Ganea, P.L. Almeida, Eur. Phys. J. Plus 133, 159 (2018). https://doi.org/10.1140/epjp/i2018-11997-8

    Article  Google Scholar 

  17. D. Manaila-Maximean, C. Rosu, Mol. Cryst. Liq. Cryst. 413(1), 9 (2004). https://doi.org/10.1080/15421400490432506

    Article  Google Scholar 

  18. P. Selvaraj, K. Subramani, B. Srinivasan, C.J. Hsu, C.Y. Huang, Sci. Rep. 10, 14273 (2020)

    Article  ADS  Google Scholar 

  19. B.P. Singh, S. Sikarwar, K.K. Pandey, R. Manohar, M. Depriester, D.P. Singh, Electron. Mater. 2, 466 (2021)

    Article  Google Scholar 

  20. R. Basu, D. Kinnamon, N. Skaggs, J. Womack, J. Appl. Phys. 119, 185107–185117 (2016)

    Article  ADS  Google Scholar 

  21. C.P. Ganea, D. Manaila Maximean, V. Cîrcu, Eur. Phys. J. Plus 135(10), 797 (2020)

    Article  Google Scholar 

  22. Y.G. Marinov, G.B. Hadjichristov, P.M. Rafailov, S.H. Lin, V.M. Marinova, A.G. Petrov, J. Phys. Conf. Ser. 1186, 012031 (2019)

    Article  Google Scholar 

  23. S. Aya, F. Araoka, Nat. Commun. 11, 3248 (2020)

    Article  ADS  Google Scholar 

  24. J. Sakuda, E. Hosono, M. Yoshio, T. Ichikawa, T. Matsumoto, H. Ohno, H. Zhou, T. Kato, Adv. Funct. Mater. 25(8), 1206 (2015)

    Article  Google Scholar 

  25. X. Cao, J. Cheng, X. Zhang, D. Zhou, Y. Tong, Int. J. Electrochem. Sci. 15, 677 (2020). https://doi.org/10.20964/2020.01.32

    Article  Google Scholar 

  26. Y. Tong, L. Chen, X. He, Y. Chen, Electrochim. Acta 118, 33 (2014)

    Article  Google Scholar 

  27. M. Baibarac, I. Baltog, T. Velula, I. Oasuk, S. Lefrant, N. Gautier, J. Phys. Cond. Matter 21, 445801 (2009)

    Article  ADS  Google Scholar 

  28. I. Baltog, M. Baibarac, S. Lefrant, P. Gomez-Romero, J. Nanosci. Nanotechnol. 9(10), 6204 (2009)

    Article  Google Scholar 

  29. I. Baltog, M. Baibarac, S. Lefrant, J.Y. Mevellec, Diam. Relat. Mater. 17(7–10), 1558 (2008)

    Article  ADS  Google Scholar 

  30. M. Baibarac, I. Baltog, S. Lefrant, P. Gomez-Romero, Mater. Sci. Eng. B 176(2), 110 (2011)

    Article  Google Scholar 

  31. O. Yaroshchuk, S. Tomylko, O. Kovalchuk, N. Lebovka, Carbon 68, 389 (2014)

    Article  Google Scholar 

  32. S. Irle, H. Lischka, J. Molec. Struct. (Theochem) 364, 15 (1996)

    Article  Google Scholar 

Download references

Acknowledgements

The authors thank the funding of the work by the Romanian Government Ministry of Research, Innovation and Digitization through National Core Founding Program (PN19-03 contract no. 21N/2019). The initiation of preliminary studies on the ability of the E7 nematic mixture for potential applications in the field of rechargeable Li batteries was inspired by S. Frunza.

Author information

Authors and Affiliations

Authors

Contributions

MB performed the electrochemical deposition, RAMAN and electrochemical analysis. MB wrote and revised the paper. IZ performed the contact angle measurements and revised the paper. CPG performed the image processing and revised the paper. LF designed and supervised the works, wrote and revised the paper.

Corresponding author

Correspondence to Ligia Frunza.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Baibarac, M., Zgura, I., Ganea, C.P. et al. Surface species of the nematic mixture E7 obtained by electrochemical insertion of Li+ ions. Eur. Phys. J. E 46, 26 (2023). https://doi.org/10.1140/epje/s10189-023-00280-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1140/epje/s10189-023-00280-z

Navigation