N-Type Doping Properties and Electronic States of Poly(2,5-thienylene vinylene)

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Copyright (c) 1992 The Japan Society of Applied Physics
, , Citation Mitsuyoshi Onoda et al 1992 Jpn. J. Appl. Phys. 31 1107 DOI 10.1143/JJAP.31.1107

1347-4065/31/4R/1107

Abstract

Evidence for electrochemical n-type doping of poly(2,5-thienylene vinylene) (PTV) is obtained from in situ measurements of a cyclic voltammogram, optical absorption spectrum and electron spin resonance. Bipolaron levels in the gap states appear upon n-type doping and the electronic band scheme of PTV is discussed.

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10.1143/JJAP.31.1107