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Extrinsic Photocarrier Generation at Fluorenone Bisazo Pigment/α-Phenylstilbene Derivative Interface

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Copyright (c) 1994 The Japan Society of Applied Physics
, , Citation Minoru Umeda Minoru Umeda and Tatsuya Niimi Tatsuya Niimi 1994 Jpn. J. Appl. Phys. 33 L1789 DOI 10.1143/JJAP.33.L1789

1347-4065/33/12B/L1789

Abstract

We have investigated the molecular interface between an azo pigment and an α-phenylstilbene derivative where photocarriers are extrinsically produced from a microscopic viewpoint. From the measurement of the azo-pigment photoluminescence quenching by the α-phenylstilbene derivative, only the molecules that contact with the azo-pigment particles are known to promote generation of the photocarriers. The electron-transfer reaction at the interface for photocarrier generation is proven to occur adiabatically.

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10.1143/JJAP.33.L1789