Deposition of Ruthenium Nanoparticles on Carbon Aerogels for High Energy Density Supercapacitor Electrodes

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© 1997 ECS - The Electrochemical Society
, , Citation J. M. Miller et al 1997 J. Electrochem. Soc. 144 L309 DOI 10.1149/1.1838142

1945-7111/144/12/L309

Abstract

The preparation and characterization of high surface area ruthenium/carbon aerogel composite electrodes for use in electrochemical capacitors is reported. These new materials have been prepared by the chemical vapor impregnation of ruthenium into carbon aerogels to produce a uniform distribution of adherent ≈20 Å nanoparticles on the aerogel surface. The electrochemically oxidized ruthenium particles contribute a pseudocapacitance to the electrode and dramatically improve the energy storage characteristics of the aerogel. These composites have demonstrated specific capacitances in excess of 200 F/g, in comparison to 95 F/g for the untreated aerogel.

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