Abstract
Characteristics for sensing of a oxide capacitor were studied. The capacitances of mixed with, , , and are dependent on the concentration, similar to . In particular, the mixed oxide, , is more sensitive to than , but requires a rather long time to recover. On the other hand, the mixed oxide capacitor, , exhibits high sensitivity, and a monotonic and approximately logarithmic relationship exists between the sensitivity and the concentration of from 100 ppm to 50%. Furthermore, the capacitance of increased rapidly within 30 s after exposure to 2% , and returned rapidly to the original level after reexposure to air. Therefore, the system, is promising for sensing over a wide range of concentrations. From a complex impedance measurement, the equivalent circuit of the sensor element can be expressed by a series connection of three parallel resistors and capacitors which correspond to the intragrain region, grain interface between and , and electrode interface. Since exposure of the element to 2% varied the capacitance of the grain interface, the grain interface between and has an important role for detection.