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Application of a Mixed Oxide Capacitor to the Selective Carbon Dioxide Sensor: II . Sensing Characteristics of a Oxide Capacitor

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© 1992 ECS - The Electrochemical Society
, , Citation Tatsumi Ishihara et al 1992 J. Electrochem. Soc. 139 2881 DOI 10.1149/1.2068999

1945-7111/139/10/2881

Abstract

Characteristics for sensing of a oxide capacitor were studied. The capacitances of mixed with, , , and are dependent on the concentration, similar to . In particular, the mixed oxide, , is more sensitive to than , but requires a rather long time to recover. On the other hand, the mixed oxide capacitor, , exhibits high sensitivity, and a monotonic and approximately logarithmic relationship exists between the sensitivity and the concentration of from 100 ppm to 50%. Furthermore, the capacitance of increased rapidly within 30 s after exposure to 2% , and returned rapidly to the original level after reexposure to air. Therefore, the system, is promising for sensing over a wide range of concentrations. From a complex impedance measurement, the equivalent circuit of the sensor element can be expressed by a series connection of three parallel resistors and capacitors which correspond to the intragrain region, grain interface between and , and electrode interface. Since exposure of the element to 2% varied the capacitance of the grain interface, the grain interface between and has an important role for detection.

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10.1149/1.2068999