The Carbon Monoxide, Carbon Dioxide and Carbon Monoxide Electrodes in Molten Alkali Carbonates

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© 1969 ECS - The Electrochemical Society
, , Citation P. K. Lorenz and G. J. Janz 1969 J. Electrochem. Soc. 116 1061 DOI 10.1149/1.2412210

1945-7111/116/8/1061

Abstract

The potentials of cells and have been determined in the ternary eutectic between 510° and 800°C. At 800°C the potential resulting from the cell indicated that the reaction occurring at the Au electrode was . At 700°C and lower, the cell potential confirmed that the reaction dominates the high partial pressure range. At lower temperatures the reaction was observed to proceed to the right, consuming part of the incoming stream so that the cell potential appeared to deviate from the Nernst slope (corresponding to the reaction ). The Nernst slopes and cell potentials follow the thermodynamic prediction for the electrochemical reactions occurring at the Au electrode.

The potentials resulting from the cell were in agreement with the thermodynamically calculated potential for the reaction occurring on the Au electrode between 510° and 670°C. At low flow rates over the entire temperature range and at all flow rates at higher temperatures the cell potential differed considerably from the predictions for the above reaction. The reaction is seen as a possible explanation for this behavior.

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10.1149/1.2412210