Biosynthesis of Silver Nanoparticles Using Coriandrum Sativum Leaf Extract and Their Application in Nonlinear Optics

We present a simple and eco-friendly biosynthesis of silver nanoparticles using Coriandrum sativum leaf extract as reducing agent. The aqueous silver ions when exposed to leaf extract were reduced and resulted in silver nanoparticles whose average size was 26 nm. The silver nanoparticles were characterized by UV-Visible, X-ray diffraction (XRD), Fourier transform infra-red spectroscopy (FT-IR) and transmission electron microscopy (TEM) techniques. Nonlinear optical properties of silver nanoparticles were studied using Z-scan technique with 6 ns pulse duration at 532 nm. The nonlinear refractive index and third-order susceptibility |χ³| were measured to be –6.0 × 10^–13 cm²/W and 1.38 × 10^–9 esu, respectively. Silver nanoparticles were found to exhibit strong reverse saturable absorption (RSA). RSA was identified as the main mechanism responsible for optical limiting.