ABSTRACT

From the Author's Preface: There is a growing demand for ultrapure organic compounds such as fine chemicals, pharmaceuticals, and basic materials for use in the polymer industry. . . . In quite a number of cases, it is difficult or impossible to manufacture ultrapure organics efficiently using conventional separation techniques such as distillation. Moreover, conventional techniques usually require large amounts of energy.  To improve the purification efficiency of organics, special techniques based on crystallization from the melt have been developed. Melt crystallization meets industry's need for a highly selective separation process for organic compounds which operates at low enough temperatures to prevent thermal degradation. Melt crystallization processes have the added advantage that they are energy-efficient and ecologically sound.  Melt crystallization techniques appear to be particularly promising for upgrading organic materials and are one of the few routes that appear to be feasible for purifying starter materials for high-tech polymers. The aim of this book is to provide basic information on melt crystallization technology. . . . This monograph consists of three parts: 1. basic principles, 2. process options, and 3. technical equipment and applicability.  This new book is the first unified guide and reference to an important chemical process technology. It is comprehensive and organized for easy reference. More than 150 diagrammatic representations, flow charts and photographs illustrate equipment and processes. More than 40 tables provide useful reference data.

part I|120 pages

Basic Principles

chapter Chapter 1|16 pages

Prospect of Melt Crystallization

chapter Chapter 2|37 pages

Basic Principles in Crystallization

chapter Chapter 3|27 pages

Thermodynamic Limits

chapter Chapter 4|18 pages

Kinetic Limits

chapter Chapter 5|18 pages

Further Purification

part II|115 pages

Process Options

chapter Chapter 6|22 pages

Layer Growth

chapter Chapter 7|27 pages

Suspension Growth

chapter Chapter 8|24 pages

Crystal-Melt Separation

chapter Chapter 9|16 pages

On the Choice of the Process Option

chapter Chapter 10|23 pages

Melt Crystallization’s Feasibility

part III|123 pages

Technical Equipment, Applicability

chapter Chapter 12|25 pages

Technical Equipment for Suspension Growth

chapter Chapter 13|31 pages

Technical Applicability

chapter Chapter 15|22 pages

Related Fields of Application

chapter Chapter 16|5 pages

Status of Development, Future Outlook