KINETICS OF LIQUID PHASE OXIDATION OF CUMENE IN BUBBLE COLUMN
1970 Volume 3 Issue 1 Pages 72-78
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1970 Volume 3 Issue 1 Pages 72-78
Liquid phase oxidation of cumene in the absence of solvent was carried out in a bubble column in temperature range from 100°C to 130°C. The reaction scheme in the batch-wise operation was classified in terms of three periods: the induction, the steady chain-propagation and the termination periods. The kinetics in the steady chain-propagation period, which is industrially important, was studied and the rate expressions of chemical steps were derived.
