Agricultural and Biological Chemistry
Online ISSN : 1881-1280
Print ISSN : 0002-1369
ISSN-L : 0002-1369
Minor Constituents of Japanese Ho-Leaf Oil
The Structures of (+)-Tagetonol and (-)-trans-Hotrienol
Toshio YOSHIDAShigeru MURAKIHiroshi KAWAMURA
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JOURNAL FREE ACCESS

1969 Volume 33 Issue 3 Pages 343-352

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Abstract

The main component of Japanese Ho-leaf oil has been shown to be (-)-linalool (80_??_90%), and the following twenty minor constituents newly have been identified; methyl vinyl ketone, methyl isobutyl ketone, mesityl oxide, β-pinene, myrcene, (+)-limonene, cis- and trans-ocimene, n-hexanol, cis-3-hexenol, cis- and trans-linalool oxide, (-)-l-terpinen-4-ol, (+)-cis. and (+)-trans-2, 6, 6-trimethyl-2-vinyl-5-hydroxytetrahydropyran, citronellol, nerol, (+)-β-selinene, (+)-tagetonol and (-)-trans-hotrienol. (+)-Tagetonol and (-)-trans-hotrienol have been demonstrated to be (+)-3, 7-dimethyl-3-hydroxy-l-octen-5-one (III) and (3R)-(-)-trans-3, 7-dimethyl-3-hydroxy-1, 5, 7-octatriene (IX), respectively.

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