Abstract
Investigations into olefin ring-closing metathesis (RCM) have led to a general method for the synthesis of coumarins. Catalysts with higher activity, such as the second-generation ruthenium catalyst, promote the intramolecular reaction between two-electron deficient olefins. This method allows for convenient access to a variety of coumarins substituted at both the 3- and 4-positions, as well as a tetrasubstituted example.
Conference
International Conference on Organometallic Chemistry (ICOMC), International Conference on Organometallic Chemistry, ICOMC, Organometallic Chemistry, XXth, Corfu, Greece, 2002-07-07–2002-07-12
Published Online: 2009-01-01
Published in Print: 2003-01-01
© 2013 Walter de Gruyter GmbH, Berlin/Boston