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Characterizations for Vinylimidazolium Based Ionic Liquid Polymer Stationary Phases for Capillary Gas Chromatography

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Abstract

Six polyvinylimidazolium based ionic liquids were prepared for use as stationary phases for gas chromatography. The influences of the attached side-chains (hexyl-, octyl- and phenylpropyl-) on the vinylimidazolium cations and of different counter ions (bromide, hexafluorophosphate, bis-trifluoromethanesulfonlyimide, and bis-trifluoroethanesulfonylimide) were studied. Linear solubility parameter experiments were conducted to characterize the specific interactions of these stationary phases. Some of the polymerized ionic liquid stationary phases exhibited unique structural selectivity. m-, and p-xylenes could be distinguished. The preparation of the polymerized ionic liquid column is simple and reliable. This work provides detailed information for designing polymerized ionic liquids, and shows that these materials have great potential extending the range of options for stationary phases in gas chromatography.

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Acknowledgement

The authors are grateful to Professors Hui-Lien Tsai, Hua-Fen Hsu, Ching-Yun Hsu, and Shao-Pin Wang for their generous help in this work, and the National Science Council for financial support (NSC. 95–2113-M-006-018).

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Authors and Affiliations

  1. Department of Chemistry, National Cheng Kung University, No.1, Ta-Hsueh Road, Tainan, 70101, Taiwan, ROC

    Yu-Nung Hsieh, Thou-Jen Whang & Chun-Hsiung Kuei

  2. Department of Chemical Engineering, I-Shou University, Kaohsiung, 1 Sec. 1, Syuecheng Road, Dashu Township, Kaohsiung County, Kaohsiung, Taiwan, ROC

    Richard S. Horng

  3. Department of Cosmetic Science, Chia Nan University of Pharmacy and Science, 60 Erh-Jen Road, Sec.1 Pao-An, Jen-Te Hsiang, Tainan, 717, Taiwan, ROC

    Wen-Yueh Ho

  4. Department of Chemical and Materials Engineering, Cheng Shiu University, 840, Cheng Ching Road, Niaosong, Kaohsiung, 83347, Taiwan, ROC

    Ping-Chih Huang & Ching-Yun Hsu

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  1. Yu-Nung Hsieh
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  2. Richard S. Horng
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  3. Wen-Yueh Ho
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  4. Ping-Chih Huang
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  5. Ching-Yun Hsu
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  6. Thou-Jen Whang
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  7. Chun-Hsiung Kuei
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Correspondence to Chun-Hsiung Kuei.

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Hsieh, YN., Horng, R.S., Ho, WY. et al. Characterizations for Vinylimidazolium Based Ionic Liquid Polymer Stationary Phases for Capillary Gas Chromatography. Chroma 67, 413–420 (2008). https://doi.org/10.1365/s10337-008-0531-8

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  • DOI: https://doi.org/10.1365/s10337-008-0531-8

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