Skip to content
Licensed Unlicensed Requires Authentication Published by De Gruyter October 25, 2018

Designing an olive tree pruning biorefinery for the production of bioethanol, xylitol and antioxidants: a techno-economic assessment

  • Ana Susmozas EMAIL logo , Antonio D. Moreno , Juan M. Romero-García , Paloma Manzanares and Mercedes Ballesteros
From the journal Holzforschung

Abstract

Olive tree crops, extensively cultivated in Southern European countries, yield large amounts of olive tree pruning (OTP) biomass. This could be used within the framework of a bio-based economy that maximizes the utilization of biomass resources in a sustainable way. In the present work, the techno-economic feasibility of an OTP-based integrated biorefinery is evaluated by the process simulation software Aspen Plus, while the process is aimed at the production of ethanol, xylitol, antioxidants and electricity. Overall, the proposed plant could perform economically, and it is self-sufficient from an energy resource point of view. The plant as designed yields around 109 l of ethanol, 27 kg of xylitol and 43 kg of antioxidants per ton of OTP biomass, with an estimated production cost of 0.24 € l−1, 1.48 € kg−1 and 5.12 € kg−1, respectively. In a 10-year period, the economic profitability of the biorefinery plant is within a positive investment balance, with a net present value (NPV) of 32.1 M€ and a payback period of 5–6 years. These figures point out the opportunities for placing in the market several OTP-based products. Based on these data, the construction of small-scale OTP-based lignocellulosic biorefineries seems to be a realistic scenario.

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: The authors thank funding from the Spanish Ministry of Economy and Competitiveness (MINECO) under the Projects SMIBIO (PCIN-2015-056) and BIOROLSOS (ENE2014-60090-C2-1-R).

  3. Employment or leadership: None declared.

  4. Honorarium: None declared.

References

Abdul-Khalek, N. (2018) Evaluación de la producción de etanol y xilitol mediante procesos fermentativos a partir de paja de cebada pretratada por explosión por vapor. Master Thesis – Universidad Complutense de Madrid, Madrid, Spain.Search in Google Scholar

Ballesteros, I., Ballesteros, M., Cara, C., Sáez, F., Castro, E., Manzanares, P., Negro, M.J., Oliva, J.M. (2011) Effect of water extraction on sugars recovery from steam exploded olive tree pruning. Bioresour. Technol. 102:6611–6616.10.1016/j.biortech.2011.03.077Search in Google Scholar PubMed

Bank of Spain (2017) Interest rate. https://clientebancario.bde.es/pcb/es/menu-horizontal/productosservici/relacionados/tiposinteres/. Last accessed date: April 23, 2018.Search in Google Scholar

Barta, Z., Reczey, K., Zacchi, G. (2010) Techno-economic evaluation of stillage treatment with anaerobic digestion in a softwood-to-ethanol process. Biotechnol. Biofuels 3:21.10.1186/1754-6834-3-21Search in Google Scholar PubMed PubMed Central

Cardona, C.A., Solarte-Toro, J.C., Peña, A.G. (2018) Fermentation, thermochemical and catalytic processes in the transformation of biomass through efficient biorefineries. Catal. Today 302:61–72.10.1016/j.cattod.2017.09.034Search in Google Scholar

Chovau, S., Degrauwe, D., Van der Bruggen, B. (2013) Critical analysis of techno-economic estimates for the production cost of lignocellulosic bio-ethanol. Renew. Sust. Energ. Rev. 26:307–321.10.1016/j.rser.2013.05.064Search in Google Scholar

Conde, E., Cara, C., Moure, A., Ruiz, E., Castro, E., Dominguez, H. (2009) Antioxidant activity of the phenolic compounds released by hydrothermal treatment of olive tree pruning. Food Chem. 114:806–812.10.1016/j.foodchem.2008.10.017Search in Google Scholar

Consorcio de aguas (2018) Tarifas de agua y saneamiento. https://oficinavirtual.consorciodeaguas.com/FacturaElectronica/ AtencionCliente/tarifas.aspx. Last accessed date: April 23, 2018.Search in Google Scholar

Dávila, J.A., Rosenberg, M., Cardona, C.A. (2017) A biorefinery for efficient processing and utilization of spent pulp of Colombia Andes Berry (Rubus glaucus Benth.): experimental, techno-economic and environmental assessment. Bioresour. Technol. 223:227–236.10.1016/j.biortech.2016.10.050Search in Google Scholar PubMed

Díaz, M., Huijgen, W., van der Laan, R., Reith, J.H., Cara, C., Castro, E. (2011) Organosolv pretreatment of olive tree biomass for fermentable sugars. Holzforschung 65:177–183.10.1515/hf.2011.030Search in Google Scholar

European Commission (2015) From the sugar platform to biofuels and biochemicals. Final report for the European Commission Directorate-General Energy. N°ENER/C2/423-2012/s12.673791.Search in Google Scholar

García Martín, J., Sánchez, S., Bravo, V., Cuevas, M., Rigal, L., Gaset, A. (2010) Xylitol production from olive-pruning debris by sulphuric acid hydrolysis and fermentation with Candida tropicalis. Holzforschung 65:59–65.10.1515/hf.2010.113Search in Google Scholar

Gnansounou, E., Dauriat, A. (2010) Techno-economic analysis of lignocellulosic ethanol: a review. Bioresour. Technol. 101:4980–4991.10.1016/j.biortech.2010.02.009Search in Google Scholar PubMed

Humbird, D., Davis, R., Tao, L., Kinchin, C., Hsu, D., Aden, A, Schoen, P., Lukas, J., Olthof, B., Worley, M., Sexton, D., Dudgeon, D. (2011) Process design and economics for biochemical conversion of lignocellulosic biomass to ethanol: Dilute-acid pretreatment and enzymatic hydrolysis of corn stover. Technical Report NREL/TP 5100 47764, National Renewable Energy Laboratory, Golden, Colorado. https://www.osti.gov/servlets/purl/1013269. Last accessed date: April 24, 2018.10.2172/1013269Search in Google Scholar

ICIS (2018) Indicatives Chemical Prices A-Z. https://www.icis.com/chemicals/channel-info-chemicals-a-z/. Last accessed date: April 24, 2018.Search in Google Scholar

INE (2017) Salarios y costes laborales. http://www.ine.es/dyngs/INEbase/es/categoria.htm?c=Estadistica_P&cid=1254735976596. Last accessed date: April 24, 2018.Search in Google Scholar

Johnson, E. (2016) Modeling and analysis integrated enzyme production lowers the cost of cellulosic ethanol. Biofuels. Bioprod. Bioref. 10:1064–1074.10.1002/bbb.1634Search in Google Scholar

Kolfschoten, R.C., Bruins, M.E., Sanders, J.P. (2014) Opportunities for small-scale biorefinery for production of sugar and ethanol in the Netherlands. Biofuels, Bioprod. Bioref. 8:475–486.10.1002/bbb.1487Search in Google Scholar

Larsson, S., Reimann, A., Nilvebrant, N.O., Jönsson, L.J. (1999) Comparison of different methods for the detoxification of lignocellulose hydrolyzates of spruce. Appl. Biochem. Biotechnol. 77:91–103.10.1007/978-1-4612-1604-9_9Search in Google Scholar

Lopez, F.J., Pinzi, S., Ruiz, J.J., Lopez, A., Dorado, M.P. (2010) Economic viability of the use of olive tree pruning as fuel for heating system in publics institutions in South Spain. Fuel 89:1386–1391.10.1016/j.fuel.2009.11.003Search in Google Scholar

Mäkinen, K.K. (1994) Sugar alcohols. In: Functional Foods: Designer Foods, Pharmafoods, Nutraceuticals. Ed. Goldberg, I., Springer, Boston, USA. pp. 219–241.10.1007/978-1-4615-2073-3_11Search in Google Scholar

Manzanares, P., Ruiz, E., Ballesteros, M., Negro, M.J., Gallego, F.J., López-Linares, J.C., Castro, E. (2017) Residual biomass potential in olive tree cultivation and olive oil industry in Spain: valorization proposal in a biorefinery context. Span. J. Agric. Res. 15:e0206.10.5424/sjar/2017153-10868Search in Google Scholar

Ministry of Finance and Public Administration (2015) Government approves fiscal reform to reduce taxes to 20 million tax payers. http://www.minhafp.gob.es/Documentacion/Publico/GabineteMinistro/Notas%20Prensa/2014/S.E.%20HACIENDA/01-08-14%20Nota%20aprobaci%C3%B3n%20reforma%20fiscal.pdf. Last accessed date: April 23, 2018.Search in Google Scholar

Moncada, J., El-Halwagi, M.M., Cardona, C.A. (2013) Techno-economic analysis for a sugarcane biorefinery: Colombian case. Bioresour. Technol. 135:533–543.10.1016/j.biortech.2012.08.137Search in Google Scholar PubMed

Moreno, A.D., Alvira, P., Ibarra, D., Tomás-Pejó, E. (2017) Production of ethanol from lignocellulosic biomass. In: Production of Platform Chemicals from Sustainable Resources. Biofuels and Riorefineries. Eds. Fang, Z., Smith, Jr. R., Qi, X. Springer, Singapore. pp. 375–410.10.1007/978-981-10-4172-3_12Search in Google Scholar

Mussatto, S.I., Moncada, J., Roberto, I.C., Cardona, C.A. (2013) Techno-economic analysis for brewer’s spent grains use on a biorefinery concept: the Brazilian case. Bioresour. Technol. 148:302–310.10.1016/j.biortech.2013.08.046Search in Google Scholar PubMed

Negro, M.J., Alvarez, C., Ballesteros, I., Romero, I., Ballesteros, M., Castro, E., Manzanares, P., Moya, M., Oliva, J.M. (2014) Ethanol production from glucose and xylose obtained from steam exploded water-extracted olive tree pruning using phosphoric acid as catalyst. Bioresour. Technol. 153:101–107.10.1016/j.biortech.2013.11.079Search in Google Scholar PubMed

NREL. Biomass compositional analysis laboratory procedures. https://www.nrel.gov/bioenergy/biomass-compositional-analysis.html. Last accessed date: April 24, 2018.Search in Google Scholar

Prakasham, R.S., Rao, R.S., Hobbs, P.J. (2009) Current trends in biotechnological production of xylitol and future prospects. Curr. Trends. Biotechnol. Pharm. 3:8–36.Search in Google Scholar

Quintero, J.A., Cardona, C.A. (2011) Process simulation of fuel ethanol production from lignocellulosics using Aspen Plus. Ind. Eng. Chem. Res. 50:6205–6212.10.1021/ie101767xSearch in Google Scholar

Quintero, J.A., Moncada, J., Cardona, C.A. (2013) Techno-economic analysis of bioethanol production from lignocellulosic residues in Colombia: a process simulation approach. Bioresour. Technol. 139:300–307.10.1016/j.biortech.2013.04.048Search in Google Scholar PubMed

Rivas, B., Torre, P., Domínguez, J.M., Converti, A., Parajó, J.C. (2006) Purification of xilitol obtained by fermentation of corncob hydrolysates. J. Agric. Food Chem. 54:4430–4435.10.1021/jf053156xSearch in Google Scholar PubMed

Romero-García, J.M., Sanchez, A., Rendón-Acosta, G., Martínez-Patiño, J.C., Ruiz, E., Magaña, G., Castro, E. (2016) An olive tree pruning biorefinery for co-producing high value-added bioproducts and biofuels: economic and energy efficiency analysis. Bioenerg. Res. 9:1070–1086.10.1007/s12155-016-9786-3Search in Google Scholar

Ruiz, E., Romero-García, J.M., Romero, I., Manzanares, P., Negro, M.J., Castro, E. (2017) Olive-derived biomass as a source of energy and chemicals. Biofuels, Bioprod. Bioref. 11:1077–1094.10.1002/bbb.1812Search in Google Scholar

Sáez, F., Álvarez, C., Ballesteros, I., Ballesteros, M., Manzanares, P., Negro, M.J., Oliva, J.M. (2012) Second-generation ethanol production from olive tree pruning. In: Advanced Biofuels in a Biorefinery Approach (February 28 – March 1, 2012, Copenhagen, Denmark). Ed. Jørgensen, H., Forest & Landscape Working Papers No. 70-2012. Frederiksberg, Denmark. p. 68.Search in Google Scholar

Ulrich, G.D., Vasudevan, P.T. (2006) How to estimate utility cost. Chem. Eng. 2006:66–69.Search in Google Scholar

Velázquez-Martí, B., Fernández-González, E., López-Cortés, I., Salazar-Hernández, D.M. (2011) Quantification of the residual biomass obtained from pruning of trees in Mediterranean olive groves. Biomass Bioenerg. 35:3208–3217.10.1016/j.biombioe.2011.04.042Search in Google Scholar

Veneziani, G., Novelli, E., Esposto, S., Taticchi, A., Servili, M. (2017) Applications of recovered bioactive compounds in food products. In: Olive Mill Waste. Ed. Galanakis, C.M., Academic Press, London (UK), San Diego (USA), Cambridge (USA), Oxford (UK). pp. 231–253.10.1016/B978-0-12-805314-0.00011-XSearch in Google Scholar

Wooley, R., Putsche, V. (1996) Development of an ASPEN PLUS physical property database for biofuels components. Technical Report NREL/TP 425 20685, National Renewable Energy Laboratory, Golden, Colorado. https://www.osti.gov/servlets/purl/257362. Last accessed date: April 24, 2018.10.2172/257362Search in Google Scholar

Received: 2018-04-30
Accepted: 2018-09-27
Published Online: 2018-10-25
Published in Print: 2018-12-19

©2019 Walter de Gruyter GmbH, Berlin/Boston

Downloaded on 3.5.2024 from https://www.degruyter.com/document/doi/10.1515/hf-2018-0099/html
Scroll to top button