Abstract
Three new layered copper hydrogen selenite nitrates, (ANO3)[Cu(HSeO3)2] (A = Cs, and Tl), and (RbNO3)2[Cu(HSeO3)2] have been prepared via isothermal evaporation of concentrated nitric acid solutions. The Tl and Cs compounds adopt a motif related to previously known (NH4Cl)[Cu(HSeO3)2]; the structure of the Rb compound represents a new structure type. The structures of (ANO3)[Cu(HSeO3)2] (A = Cs, Tl), (RbNO3)2[Cu(HSeO3)2], and (NH4NO3)3[Cu(HSeO3)2] form a unique homological series distantly related to Ruddlesden – Popper series of layered perovskites.
Dedicated to: Professor Dr. Dr. h.c. Wulf Depmeier on the occasion of his 75th birthday.
Acknowledgements
This work was financially supported by the Russian President grant MD-5229.2018.5. Technical support by the X-Ray Diffraction and Microscopy and Microanalysis Resource Centers of Saint-Petersburg State University is gratefully acknowledged.
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