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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Oxygen Diffusion in YBa2Cu3O7–δ Studied via 133Ba(EC)133Cs Nuclear Quadrupole Interaction

  • W. Tröger and T. Butz
From the journal Zeitschrift für Naturforschung A
https://doi.org/10.1515/zna-1992-1-205
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Abstract

The oxygen diffusion in YBa2Cu3O7-δ was studied between 300 K and 1273 K in flowing oxygen by monitoring the 133Ba(EC)133 Cs nuclear quadrupole interaction by time differential perturbed angular correlation. The data are analyzed in a model of two different nearest neighbour oxygen configurations and yield hopping rates, the energy barrier and the difference in free enthalpy between both states. In addition, we studied the reduced system YBa2Cu3O6 +ε.

Received: 1991-8-9
Published Online: 2014-6-2
Published in Print: 1992-2-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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From the journal
Zeitschrift für Naturforschung A
Zeitschrift für Naturforschung A
Volume 47 Issue 1-2
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Inhaltsverzeichnis
Preface
Probing the Electronic Structure of Y-Ba-Cu-O Superconductors by Copper NQR/NMR
NQR and NMR in High Tc Superconductors
Oxygen Diffusion in YBa2Cu3O7–δ Studied via 133Ba(EC)133Cs Nuclear Quadrupole Interaction
Cu NQR Study in a High-Jc Superconductor YBa2Cu3O6.1Ix
Cu-NQR Frequencies and Linewidths in High- Tc Superconductors
NQR Studies of the Structure of Glasses and Crystalline Compounds
14N Quadrupole Interactions in Nitrogen-Containing Ceramics. Effects on 29Si NMR Line Shapes and Structural Implications
Electric Field Gradient in Aluminium due to Vacancy and Muon
Nucleus-Carrier Interactions in the Group V Semimetals: Dependence on Temperature and Pressure
Cesium Iodometallates(III), Cs3M2I9, with M = Rare Earth. A Structural Investigation by 127I NQR
NQR and X-ray Studies of [N(CH3)4]3M2X9 and (CH3NH3)3M2X9 (M = Sb,Bi; X = Cl,Br)
Coordination of Ortho-Chlorines in Copper (I) and Silver (I) 2,6-Di- and 2,4,6-Trichlorophenolates
The Nuclear Quadrupole Interaction of 199mHg-Cysteine and 199mHg-tert-butyl-mercaptide
The 111mCd Nuclear Quadrupole Interaction in CdCl2 and its Monohydrate
14N NQR in 1,10-Phenanthroline and Dicyano bis(1,10-phenanthroline)iron(III)*
81Br and 127 I NQR Studies of (CH3NH3)2HgBr4 and (CH3NH3)2HgI4
A63,65Cu and 127I Nuclear Quadrupole Resonance and X-Ray Crystallographic Study of a Low-Temperature Phase of the (2-picoline) Copper (I) Iodide Dimer
7Li-Solid-State-NMR of [Li(N,N,N',N'-Tetramethylethylenediamine)] CLO4 and [Li (N,N,N', N'-Tetramethylethylenediamine)2] Al(CH3)4
An NQR Study of Tetrachloride Complexes of Group IVA Elements
63,65Cu and 79 81Br NQR Studies of Thione Complexes of Cu(I) Halides
Bromine-79 NQR for uncoordinated Br– ions in trans-[CoBr2(en)2][H5O2]Br2
Electron Effects of Adduct Formation by some Metal Halides
NQR Studies of Organic Compounds Containing Tetra- or Pentacoordinated Atoms of Elements of Groups IVA and VIA
35Cl NQR Spectra of Organyl(chloroalkyl) Sulfides
Spatial Electron Density Distribution of Chlorine Atoms in Molecules of the Series Cl2C = CXX'
Dioxin Precursors: NQR Studies of Group 1 and Related 2,6-Dichlorophenolate and 2,4,6-Trichlorophenolate Salts
35Cl NQR and Structural Studies of Chloroacetanilides C6H3Cl2NHCOCH3-xClx, 1 ≤ x ≤ 3
79Br and 127I NQR of tert-Butylammonium Halides and Crystal Structure of (CH3)3CNH3⊕ Br⊖
NQR and Crystal Structure of 4,5-Dichloroimidazole, C3H2N2Cl2
Theoretical Study of the Electric Field Gradient in Silver Iodide
The Nuclear Quadrupole Moments of the 20 First Elements: High-Precision Calculations on Atoms and Small Molecules
Ab initio Calculations of the Electric Field Gradients in Solids in Relation to the Charge Distribution
The ab initio Calculation of Nuclear Quadrupole Coupling Constants with Special Reference to 33S
14N NQR and the Molecular Charge Topology in Coordinated Ammonia
Milli-Kelvin NQR: A Study of the Praseodymium Trihalides
Electric Field Effect on 14N NQR in Ferroelectric Thiourea Single Crystals
Phase Transitions in Bis(4-chlorophenyl)sulfone as Studied by 35Cl FT-NQR
NQR Study of the Pinning and Depinning of the Incommensurate Modulation Wave in the Presence of Impurities
35Cl NQR and Crystal Structure Studies of Salts of Chlorodifluoro- and Dichloroacetic Acid
High Pressure Studies of Tetrachloro-o-benzoquinone by NQR Spectroscopy
NQR Investigation of the Temperature-Induced Neutral-to-Ionic Phase Transition in the Mixed-Stack Charge-Transfer Complex TTF-CA
Chlorine-NQR Relaxation Near the Structural Transitions of Natural and Deuterated (NH4)2TeCl6
Reorientational Motion of Trihalogenomethyl Groups in Organic Compounds as Studied by 35Cl NQR and 19F NMR Spectroscopy
Chlorine Nuclear Quadrupole Relaxation and Cationic Motion in Trimethylsulfonium Hexachloroselenate(IV): [(CH3)3S]2SeCl6
Chlorine Nuclear Spin-Spin Relaxation Mechanism in Mg(H2O)6SnCl6 as Studied by NQR and NMR Techniques
Uniaxial Reorientation of Octahedral Complex Anions Excited in Triethylammonium Hexachlorostannate (IV) Crystals
Reorientational Motion of Hydrogen Bonded Octahedral Complex Anions in Hydrazinium Hexachlorostannate(IV), (N2H5)2SnCl6, as Studied by 35Cl NQR Spin-Lattice Relaxation Measurements
Reorientation of the CCl3 Group in Chloral 4-Chlorobenzylhemiacetal. A Pulsed 35Cl NQR and X-ray Study
35Cl NQR Relaxation in Chloral Cyclohexylhemiacetal
The 35Cl NQR Temperature Dependence of Hexa- and Octachlorocyclophosphazene
NQR and Neutron Diffraction in Scheelites
Temperature dependence of the Spin-Lattice Relaxation Time of the 23Na-NMR Line in NaNO2
Sodium Ion Exchange in Na1+xZr2SixP3-xO12 as Studied by 23Na Nutation NMR
Anomalous Temperature Dependence of the 99Tc Quadrupole Coupling and Disordering of Cesium Positions in CsTcO4
35Cl NQR and Molecular Motion in Solid C6X5Cl (X = H, F)
2 D Methods in NQR Spectroscopy
Contribution of Microwave Fourier Transform Spectroscopy to the Investigation of Nuclear Quadrupole Coupling
Quadrupole Nutation NMR in Solids
NQR Imaging
Weak Complexes of Dinitrogen: An Approach to the 14N-Nuclear Quadrupole Coupling Constant of Free N2
Detection of Quadrupole Interactions by Muon Level Crossing Resonance
Two-dimensional Exchange Spectroscopy Using Pure NQR
A Simple Model to Explain 19F-TDPAD Amplitude Characteristics
A Computer-controlled, Fully Automatic NMR/NQR Double Resonance Spectrometer
Zeeman NQR Studies on Polycrystals of Copper Compounds, Arsenic Compounds, and Chlorine Compounds
NQR Spin Echo in the Effective Fields of Multiple-Pulse Sequences
Zeeman Effect of Pure NQR in a Rotating Frame (CW and Pulsed Excitation)
Experimental Investigations of the Strong Off-Resonant Comb (SORC) Pulse Sequence in 14N NQR
14N Fourier Transform Nuclear Quadrupole Resonance. Instrumentation: Measurements on Cyanuric Chloride
Two-dimensional Two-frequency NQR Spectroscopy
The Quasistationary States in Multipulse NQR
Recent Development of Nuclear Quadrupole Resonance Spectra Database
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