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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Kristallstruktur der sulfidverbrückten Gold(I)verbindung [Au{S(AuPPh3)2}2]+ [(CH3)3SnCl2]— / Crystal Structure of the Sulphide-bridged Gold(I) Complex [Au{S(AuPPh3)2}2]+[(CH3)3SnCl2]–

  • Peter G. Jones , Corneha Lensch and George M. Sheldrick
From the journal Zeitschrift für Naturforschung B
https://doi.org/10.1515/znb-1982-0205
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The compound [Au{S(AuPPh3)2}2]+[(CH3)3SnCl2]- was prepared by the reaction of Ph3PAuCl with ((CH3)3Sn)2S and characterised by an X-ray structure determination [C2/c, a = 1713.4(5), b = 2996.7(12), c = 3081.7(12) pm, β = 102.40(3)°, Z = 8, R = 0.074]. The cation displays short Au ··· Au contacts and narrow Au-S-Au angles ( < 90°). The chlorine atoms of the anion are axially arranged. There are two independent anions, one lying on, and the other disordered about, the crystallographic twofold axes

Keywords: Crystal Structure; Gold(I); Bridging Sulphide Ligand; Five-coordinate Tin(IV)
Received: 1981-10-8
Published Online: 2014-6-2
Published in Print: 1982-2-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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From the journal
Zeitschrift für Naturforschung B
Zeitschrift für Naturforschung B
Volume 37 Issue 2

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