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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Reactions of the Hexafluorothioacetone Dimer with Cyanides of Phosphorus, Arsenic and Germanium

  • Herbert W. Roesky , Kaveripatnam S. Dhathathreyan , Mathias Noltemeyer and George M. Sheldrick
From the journal Zeitschrift für Naturforschung B
https://doi.org/10.1515/znb-1985-0216
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Abstract

Cyanides such as P(CN)3 , As(CN)3 , PhP(CN)2 , ButAs(CN)2 and Ge(CN)4 react with [(CF3)2CS]2 (1) by insertion of the carbon atom of the iso-nitrile isomer into the four-membered [CS]2 ring to give compounds PR′3 (2), AsR′3 (3), FP(S)R′2 (4), PhP(S)R′2 (5), ButAsR′2 (6) and GeR′4 (7) respectively, where R′ is the novel heterocyclic ligand[xxx]. The crystal structures of 3 and 7 are reported.

: Keywords Crystal Structure; Hexafluorothioacetone; Nitriles; Heterocyclics
Received: 1984-9-19
Revised: 1984-10-25
Published Online: 2014-6-2
Published in Print: 1985-2-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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From the journal
Zeitschrift für Naturforschung B
Zeitschrift für Naturforschung B
Volume 40 Issue 2

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