Change language
English Deutsch
Change currency
€ EUR £ GBP $ USD
BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Darstellung und Eigenschaften des Tribrom-cyclo-1λ6-wolfram-3,5-dithia-2,4,6-triazens/Synthesis and Properties of Tribromo-cyclo-1λ6-tungsten-3,5-dithia-2,4,6-triazene

  • Herbert W. Roesky , Jürgen Schimkowiak , Mathias Noltemeyer and George M. Sheldrick
From the journal Zeitschrift für Naturforschung B
https://doi.org/10.1515/znb-1986-0206
Download article (PDF)

The metallacycle [Br3WS2N3] has been obtained from the reaction of S4N4 with WBr5. The salt [Ph4P+][Br4WS2N3-] was formed from [Br3WS2N3] by addition of Ph4PBr. It crystallizes in the orthorhombic space group Pbca with a = 1396.8(4), b = 1961.9(5), c = 2108.0(4) pm, and Z = 8. The following mean bond lengths were observed in the anion: W-N 184.2, W-Br 256.8, N-S 157.8 pm.

Keywords: Heterocycle; Tungsten; X-Ray; Anion; Bromine
Received: 1985-10-21
Published Online: 2014-6-2
Published in Print: 1986-2-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Download article (PDF)
From the journal
Zeitschrift für Naturforschung B
Zeitschrift für Naturforschung B
Volume 41 Issue 2

Journal and Issue

Articles in the same Issue

Bis(oxalato)platinate des Bis(oxamidoxim)platin: Anisotrope Festkörper mit gemischten und mit getrennten Stapeln/Bis(oxalato)platinate Salts of Bis(oxamide-oxime)platinum: A nisotropie Solids with Mixed and with Segregated Stacks
Neue Selen-Stickstoff-Verbindungen tert-Butyl-seleninylamin, ButNSeO, und Di(tert-butyl)selendiimid, Se(NBut)2/New Selenium-Nitrogen Compounds tert-Butyl-seleninylamine, ButNSeO, and Di(tert-butyl)selenium Diimide, Se(NBut)2
Reaktive E=C(p-p)π-Systeme, VI [1] Reaktionen des Phosphaalkens F3CP=CF2 mit H-aciden Verbindungen/Reactive E = C(p-p)π-Systems, VI [1] Reactions of the Phosphaalkene F3CP = CF2 with H Acidic Compounds
Reaktionen von 1,2,4-Thiadiazol-3,5-dicarbonitril mit Schwefelchloriden: Röntgenstrukturanalyse von S3(CN)4Cl2·AsF5 und S3(CN)8Cl2/Reactions of 1,2,4-Thiadiazol-3,5-dicarbonitrile with Sulfur Chlorides: X-Ray Crystal Structure Analysis of S3(CN)4Cl2·A sF5 and S3(CN)8Cl2
2-Boratanaphthalin-Anion als hexahapto-gebundener Ligand/2-Boratanaphthaline Anion as Hexahapto-Bonded Ligand
Darstellung und Eigenschaften des Tribrom-cyclo-1λ6-wolfram-3,5-dithia-2,4,6-triazens/Synthesis and Properties of Tribromo-cyclo-1λ6-tungsten-3,5-dithia-2,4,6-triazene
Phthalocyanines on Mineral Carriers, 2 Synthesis of Cobalt(II) and Copper(II)-phthalocyanines on γ-Al2O3 and SiO2
tert-Butylimino-δ-Organovanadium(V)-Verbindungen Darstellung und NMR-spektroskopische Untersuchungen/tert-Butylimino-δ-Organovanadium (V) Compounds Synthesis and NMR Spectroscopic Studies
Phosphiniden-, Arsiniden- und Stibiniden-Komplexe, ihre valenztautomeren Formen und Dimerisierungsprodukte/Phosphinidene-, Arsinidene- and Stibinidene Complexes, Valence Tautomerism and Dimerisation Products
Über die Nichtexistenz eines einfachen μ-oxo-Diphosphorans mit zwei 1.3.5.7-Tetramethyl-1.3.5.7-tetra-aza-4λ5-phosphaspiro[3.3]heptan- 2.6-dion-Gruppierungen: Darstellung und Struktur eines zweifach mit N,Nʹ-Dimethylharnstoff überbrückten λ5P–O–λ5P-Diphosphorans/On the Nonexistence of a Simple μ-Oxo-diphosphorane Involving two 1,3.5.7-Tetramethyl-1.3.5.7-tetra-aza-4λ5-phospha-spiro[3.3]heptane-2.6-dione Groupings: Preparation and Structure of a λ5P–O–λ5P Diphosphorane Doubly Bridged with N.Nʹ-Dimethylurea
Über die Konfigurations- und Substituenten-Abhängigkeit der 1H- und 13C-NMR-Parameter in substituierten Verbindungen vom Typ cis- und trans-Bis(phenyl)bis(tri-n-butylphosphan)platin(II)/The Dependence of 1H and 13C NMR Parameter on Configuration and Substituents in Substituted cis- and trans-Bis(phenyl)bis(tri-n-butylphosphane)platinum (II) Compounds
Synthese und Eigenschaften von 5-BenzoyItetramsäuren/Synthesis and Properties of 5-Benzoyltetramic Acids
Transanulare Wechselwirkung bei [m.n]Phanen, 32 [1]: Modelle für Amin-Aromaten-Exciplexe: [2](1,4)Anthraceno[2](2,6)pyridinophan-1,13-dien/Transanular Interaction in [m .n]Phanes, 32 [1]: Models for Amine-Arene-Exciplexes: [2](1,4)Anthraceno[2](2,6)pyridinophan-1,13-dien
Molecular Determinants for Drug-Receptor Interactions. 6. Proton 500 MHz NMR Spectra of the Narcotic Antagonists Naloxone and Naltrexone by Two-Dimensional 1H–1H Chemical Shift Correlation Spectroscopy
Synthesis of Quaternary Salts from 2,3ʹ-Bipyridine and Dibromoalkanes
Chlorination of 3,5-Di-tert-butylphenol+ Crystal Structure of the Keto Tautomer of a Sterically Hindered Phenol
Synthesis of Pyranobenzopyranopyridines and Benzodipyran Derivatives
Notizen: Notiz zur Blitzthermolyse von peri-Bis(chlormethyl)-aromaten/Note on the Flash Pyrolysis of peri-Bis(chloromethyl)-aromatic Compounds
Notizen: Darstellung und Schwingungsspektrum von Hexaiodoiridat(III), Cs3[IrI6]/Preparation and Vibrational Spectrum of Hexaiodoiridate(III), Cs3[IrI6]
Notizen: A New , Short Synthesis of Z-Jasmone
Notizen: Zur Photochromie des N-Isopropyl-4- nitrothiobenzimidsäure-methylesters/The Photochromic Reaction of Methyl N-Isopropyl-4-nitrothiobenzimidate
Downloaded on 27.4.2024 from https://www.degruyter.com/document/doi/10.1515/znb-1986-0206/html
Scroll to top button