Change language
English Deutsch
Change currency
€ EUR £ GBP $ USD
BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Synthese und Struktur von [Fe(SPh)2(NO)2]- dem „Monomeren“ des Roussinschen Phenylesters/ Synthesis and Structure of [Fe(SPh)2(NO)2]- , the “Monomer” of Roussin’s Phenyl Ester

  • Henry Strasdeit , Bernt Krebs and Gerald Henkel
From the journal Zeitschrift für Naturforschung B
https://doi.org/10.1515/znb-1986-1107
Download article (PDF)

The complex (Et4N )[Fe(SPh)2(NO)2] (2) has been obtained as black crystals by treatment of K[Fe4S3(NO)7]·H2O with potassium hydroxide in molten diphenyldisulfide and subsequent addition of methanol and tetraethylammonium chloride. 2 is orthorhombic, space group Pbca, Z = 8, with a = 18.853(3), b = 17.958(3), and c = 13.283(2) Å at 140 K. The X-ray structure of 2 has been refined to R1 (R2) = 2.7% (3.1% ). It reveals a pseudotetrahedral S2N2 arrangement around the iron atom (Fe -S 2.280, Fe -N 1.679 Å (mean values), S -Fe -S 109.73(2)°, N -Fe -N 117.36(9)°) and Fe -N -O groups of the linear type (N -O 1.180 Å , Fe -N - O 169.0° (mean values)). The N - O bond order is 2.2. Structural properties as well as the low Mößbauer isomeric shift ( + 0.08 mm/s relative to Fe metal) are indicative of strong Fe - N π-back bonding and a major contribution of the mesomeric form Fe = N = Ō̱

.

Keywords: Iron-Nitrosyl Thiolates; Synthesis; X -R ay; Roussin’s Phenyl Ester
Received: 1986-4-8
Revised: 1986-8-4
Published Online: 2014-6-2
Published in Print: 1986-11-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Download article (PDF)
From the journal
Zeitschrift für Naturforschung B
Zeitschrift für Naturforschung B
Volume 41 Issue 11

Journal and Issue

Articles in the same Issue

Transition Metal Squarates, II On the Structure of Cubic (MC4O4·2H2O)3CH3COOH·H2O(M=Zn2+,Ni2+)[1]
Übergangsmetallquadratate, III Über die trikline Käfigstruktur des (MC4O4·2 H2O)3·CH3COOH·H2O(M = Zn2+, Mn2+)/Transition Metal Squarates, III On the Triclinic Cage Structure of (MC4O4·2 H2O)3-CH3COOH·H2O(M = Zn2+, Mn2+)
Komplexe mit substituierten 2,5-Dihydroxy-p-benzochinonen: ZnC6(NO2)2O4·2 H2O/Complexes with Substituted 2,5-Dihydroxy-p-benzochinones: ZnC6(NO2)2O4·2 H2O
Synthesis and Crystal Structure of CuC4O4·2 H2O
Kubische Cyanomercurate NR4MHg(CN)4 (R = Et, Pr; M = Li, Na, K, Cu) mit Alumosilikatstruktur/On Cubic Cyanomercurates NR4MHg(CN)4 (R = Et, Pr; M = Li, Na, K, Cu) with Alumosilicate Type Structure
A TTF Derivative Acting as a Chelate Ligand: Structure of μ-[Tetra(methylthio)tetrathiafulvalene]di[diodoniercury(II)], (TTM-TTF) (HgI2)2, and the Structure of a Second Modification of Free TTM-TTF
Synthese und Struktur von [Fe(SPh)2(NO)2]- dem „Monomeren“ des Roussinschen Phenylesters/ Synthesis and Structure of [Fe(SPh)2(NO)2]- , the “Monomer” of Roussin’s Phenyl Ester
Darstellung und Kristallstruktur von Palladiumoxidchlorid Pd2OCl2/Preparation and Crystal Structure of Palladium Oxide Chloride Pd2OCl2
Borylierte Carbodiimide
Benzoatokomplexe des Rutheniums, 2. Mitt. Synthese, Eigenschaften und Kristallstruktur von Ru2(C6H5COO)2(CO)4, Ru2(C6H5COO)2(CO)6 und Ru2(CH3COO)2(CO)6/Benzoato Complexes of Ruthenium, Part 2 Synthesis, Properties and Crystal Structure of Ru2(C6H5COO)2(CO)4, Ru2(C6H5COO)2(CO)6 and Ru2(CH3COO)2(CO)6
Synthese und Kristallstruktur von Bis[1,5-ditolylpentaazadienido-thallium(I)] und Bis[1,3-diphenyltriazenido-thallium(I)]/Synthesis and Crystal Structure of Bis[1,5-Ditolylpentaazadienido-thallium(I)] and Bis[ 1,3-diphenyltriazenido-thallium(I)]
Darstellung von Chalkogenostibanen des Typs R2SbER′ (R = CH3, C2H5; E = S, Se, Te; R′ = CH3, C6H5) durch Austauschreaktionen zwischen Distibanen und Dichalkogeniden/ Preparation of Chalcogenostibanes of the Type R2SbER′ (R = CH3, C2H5; E = S, Se, Te; R′ = CH3, C6H5) by Exchange Reactions of Distibanes and Dichalcogenides
Darstellung und Kristallstrukturen von LiGaBr4 und LiGaBr3/Preparation and Crystal Structure of LiGaBr4 and LiGaBr3
Bonding in the BaPdSn3 Structure
Sr3In2P4 und Ca3ln2As4, Zintlphasen mit Bänderanionen aus kanten-und eckenverknüpften InP4- bzw. InAs4-Tetraedern/ Sr3In2P4 and Ca3In2As4, Zintl Phases with Strings of InP4 and InAs4 Tetrahedra, Resp., Sharing Edges and Corners
Kristallstruktur von β-VCl2(N3S2). Synthese und Kristallstruktur von [VCl(N3S2)(Pyridin)2]2·2 CH2Cl2, einem Cyclothiazenokomplex mit Vanadium(IV)/Crystal Structure of β-VCl2(N3S2). Synthesis and Crystal Structure of [VCl(N3S2)(pyridine)2]2·2 CH2Cl2, a Cyclothiazeno Complex with Vanadium (IV)
Synthese und Struktur von Dicarbonyl(η5-pentaphenylcyclopentadienyl)rhodium, (η5-C5Ph5)Rh(CO)2
Darstellung und Molekülstruktur des Ferrocenylkomplexes CpW(NO)2Fc und seine Oxidation zu CpWO2Fc/Synthesis and Molecular Structure of the Ferrocenyl Complex CpW(NO)2Fc and its Oxidation to CpWO2Fc
Tribromide Salts of the Organic Donor Tetra(methylthio)tetrathiafulvalene, [TTM-TTF]+(Br3-) and [TTM-TTF]2+(Br3-)2
Spectral, Magnetic and Thermogravimetric Studies of Some Dimeric Oxovanadium(IV) Complexes
Metallkomplexe mit biologisch wichtigen Liganden, XLIII Metallkomplexe mit ungeschützten acyclischen Monosaccharid-Derivaten (Amin-, Oxim-, Schiffbase-, Thiazolidin-und 1,3-Dithian-Liganden)/Metal Complexes with Biologically Important Ligands, XLIII Metal Complexes with Unprotected Acyclic Derivatives of Monosaccharides (Amine, Oxime, Schiffbase, Thiazolidine and 1,3-Dithiane Ligands)
Über Antimon-haltige Heterocyclen, V Antimon(III)-dithiolate mit verbrückten 5-und 8-Ringen/On Heterocyclic Systems Containing Antimony, V Antimony(III) Dithiolates with Bridged 5-and 8 -Membered Rings
Molecular Complexes, 8 Formation Constants and Topology of Complexes of Tetramethyluric Acid. An 1H NMR Reinvestigation Based on the AUS Concept and on the Shift Difference Method. A Revised Complex Topology
Differences between the Reaction of 2-Benzylidenecyclopentanone with Malononitrile and the Reaction of Cyclopentylidenemalononitrile with Aromatic Aldehydes; Synthesis of Strong Fluorescent o-Aminonitriles
Biflavonoide aus Schinus terebinthifolius Raddi (Anacardiaceae)/ Biflavonoids from Schinus terebinthifolius Raddi (Anacardiaceae)
The Crystal Structure of TeCl3+ AuCl4-
Downloaded on 4.5.2024 from https://www.degruyter.com/document/doi/10.1515/znb-1986-1107/html
Scroll to top button