Darstellung und Struktur des Bis(triphenylarsoranyliden)ammoniumchlorids / Preparation and Structure of Bis(triphenvlarsoranylidene) Ammonium Chloride

Herbert W. Roesky; Nobert Bertel; Frank Edelmann; Mathias Noltemeyer; George M. Sheldrick

doi:10.1515/znb-1988-0113

Open Access Published by De Gruyter June 2, 2014

Darstellung und Struktur des Bis(triphenylarsoranyliden)ammoniumchlorids / Preparation and Structure of Bis(triphenvlarsoranylidene) Ammonium Chloride

Herbert W. Roesky , Nobert Bertel , Frank Edelmann , Mathias Noltemeyer and George M. Sheldrick

From the journal Zeitschrift für Naturforschung B

https://doi.org/10.1515/znb-1988-0113

Abstract

The reaction of Ph₃AsCl₂ (1) and N(SiMe₃)₃ (2) yields [Ph₃As-N-AsPh₃]⁺Cl (3) as a crystalline white solid, soluble in CH₃OH and acetone. 3 might be used to stabilize unusual anions. It crystallizes as a 1:1 toluene adduct in the space group C2/c with a - 1585.3(3). b = 1058.7(2). c = 2266.3(4) pm. β = 94.40(2)° and Z = 4. The cation in 3 lies on a crystallographic two-fold axis with As-N-As 123.9(1)°. As-N 174.9(3). and As-C 196.7(5). 197.6(5). 193.2(5) pm.

Keywords: Arsenic; Bulky Cation X-Ray

Published Online: 2014-6-2

Published in Print: 1988-1-1

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Darstellung und Struktur des Bis(triphenylarsoranyliden)ammoniumchlorids / Preparation and Structure of Bis(triphenvlarsoranylidene) Ammonium Chloride

Abstract

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