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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Über die Reaktion von Dicyan mit Cd(II)-Ionen Röntgenstrukturanalyse von [Cd{(CN)2}2SO2 ][AsF6]2/ The Reaction of Cyanogen with Cd(II) Ions X-Ray Structure Analysis of [Cd{(CN)2}2SO2][AsF6]2

  • Herbert W. Roesky , Jürgen Schimkowiak , Mathias Noltemeyer and George M. Sheldrick

Abstract

Cd[AsF6]2 (1) reacts with cyanogen to yield [Cd{(CN)2}2SO2][AsF6]2 (2). 2 crystallizes in the space group Pnma with cell constants a = 1475.2(3); b = 821.7(3); c = 1321.2(9) pm. The coordination sphere of cadmium consists of nine atoms (one oxygen, four fluorines and four nitrogens). Cyanogen forms polymeric links.

Received: 1988-3-10
Published Online: 2014-6-2
Published in Print: 1988-8-1

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