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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Pd(II) and Pt(II) Complexes of 1,2-Bis(pyridin-2-yl)ethane-N,N'

  • A. McFarlane , J. R. Lusty , J. J. Fiol , A. Terrón , E. Molins , C. Miravitlles and V. Moreno
From the journal Zeitschrift für Naturforschung B
https://doi.org/10.1515/znb-1994-0619
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X-ray crystal structures and properties of the two Pd(II) and Pt(II) complexes [bpeH2][PdCl4] and [Pt(bpe)Cl2], [bpe = 1,2-bis(pyridin-2-yl)ethane] are described and correlated with the IR and 1H NMR/13C NMR spectroscopic data. In the case of the Pt(II) complex, the 1,2-bis(pyridin-2-yl)ethane is bound to the metal by the heterocycle nitrogen atoms but no direct bond is found in the case of the Pd(II) complex. The ligand exhibits low energy geometries in both compounds: the cis-conformation in the Pt(II) complex, and the transconformation in the Pd(II) complex

: Pyridine Pt(II) Compounds; Complexes of Pt(II) and Pd(II)
Received: 1994-1-27
Published Online: 2014-6-2
Published in Print: 1994-6-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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From the journal
Zeitschrift für Naturforschung B
Zeitschrift für Naturforschung B
Volume 49 Issue 6

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