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Licensed Unlicensed Requires Authentication Published by De Gruyter June 2, 2014

Preparation, Structure and Optical Properties of [CH3SC(NH2)2]3SnI5, [CH3SC(NH2)2][HSC(NH2)2]SnBr4, (CH3C5H4NCH3)PbBr3, and [C6H5CH2SC(NH2)2]4Pb3I10

  • C. P. Raptopoulou , A. Terzis , G. A. Mousdis and G. C. Papavassiliou
From the journal Zeitschrift für Naturforschung B
https://doi.org/10.1515/znb-2002-0609

Abstract

The preparation, crystal structure and optical absorption spectra of [CH3SC(NH2)2]3SnI5 (1), [CH3SC(NH2)2][HSC(NH2)2]SnBr4 (2), (CH3C5H4NCH3)PbBr3 (3), and [C6H5CH2SC-(NH2)2]4Pb3I10 (4) are reported. The compounds 1, 2, 3 consist of MX6-octahedra (M = Sn, Pb, X = I, Br) forming one-dimensional single chains (compounds 1, 3) or double chains (compound 2). The compound 4 forms a two-dimensional inorganic network via corner sharing of three face sharing octahedral units. Because of their low-dimensional character, a blue shift of the excitonic absorption bands, in comparison to those of higher dimensionality systems, is observed.

Keywords : Metal Halides; Excitonic Spectra; Optical Properties
Received: 2002-2-14
Published Online: 2014-6-2
Published in Print: 2002-6-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

From the journal
Zeitschrift für Naturforschung B
Zeitschrift für Naturforschung B
Volume 57 Issue 6

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