Abstract
Present study deals with use of agricultural based waste material Loquat (Eriobotrya japonica) seeds for removal of toxic Acid orange 7 (AO7) dye from aqueous streams. Batch mode experiments were conducted as function of pH, initial dye concentration, contact time and dosage of adsorbent. Biomass was used in native, pretreated and immobilized forms. Maximum removal was observed at pH 2. Desorption studies were done in order to determine degree of stability and regeneration of immobilized biomass. For equilibrium studies, Langmuir and Freundlich models were applied. Pseudo 1st & 2nd order models were applied on experimental data for reaction kinetics evaluation. Pseudo 2nd order model was best fit for present experiments. Biomass characterization was done by scanning electron microscopy (SEM), Energy dispersive X-ray (EDX) and Fourier Transform Infrared (FTIR) techniques for elucidation of biomass constituents and surface morphology before and after dye loading. It was observed that loquat seeds may be potential adsorbent for removal of toxic dyes from wastewater.
Conflict of interest: There is no conflict of interest.
References
1. J. Abdi, D. Bastani, J. Abdi, N. M. Mahmoodi, A. Shokrollahi, A. H. Mohammadi, J. Environ. Chem. Eng. 2 (2014) 1672.10.1016/j.jece.2014.06.002Search in Google Scholar
2. M. Abbas, M. Adil, S. Ehtisham-ul-Haque, B. Munir, M. Yameen, A. Ghaffar, G. A. Shar, M. A. Tahir, M. Iqbal, Sci. Tot. Environ. 626 (2018) 1295.10.1016/j.scitotenv.2018.01.066Search in Google Scholar PubMed
3. M. Iqbal, Chemosphere. 144 (2016) 785.10.1016/j.chemosphere.2015.09.048Search in Google Scholar PubMed
4. M. Iqbal, R. Khera, M. Tariq, H. Sadia, M. Abbas, A. Nazir, U. Younas, Curr. Sci. 3 (2017) 106.Search in Google Scholar
5. M. Suleman, S. Nouren, S. M. Hassan, A. H. Faiz, G. A. Sahr, G. A. Soomro, M. A. Tahir, M. Iqbal, A. Nazir, Pol. J. Environ. Stud. 27 (2018) 1407.10.15244/pjoes/76798Search in Google Scholar
6. B. Padhi, Int. J. Environ. Sci. 3 (2012) 940.Search in Google Scholar
7. M. Noreen, M. Shahid, M. Iqbal, J. Nisar, Measurement. 109 (2017) 88.10.1016/j.measurement.2017.05.030Search in Google Scholar
8. N. Nazar, I. Bibi, S. Kamal, M. Iqbal, S. Nouren, K. Jilani, M. Umair, S. Ata, Int. J. Biol. Macromol. 106 (2018) 1203.10.1016/j.ijbiomac.2017.08.126Search in Google Scholar PubMed
9. V. Gupta, J. Environ. Manage. 90 (2009) 2313.10.1016/j.jenvman.2008.11.017Search in Google Scholar PubMed
10. M. Iqbal, J. Nisar, M. Adil, M. Abbas, M. Riaz, M. A. Tahir, M. Younus, M. Shahid, Chemosphere. 168 (2017) 590.10.1016/j.chemosphere.2016.11.021Search in Google Scholar PubMed
11. M. Iqbal, Z. Ali, M. A. Qamar, A. Ali, F. Hussain, M. Abbas, J. Nisar, Water Sci. Technol. 76 (2017) 219.10.2166/wst.2017.213Search in Google Scholar PubMed
12. I. Bibi, N. Nazar, M. Iqbal, S. Kamal, H. Nawaz, S. Nouren, Y. Safa, K. Jilani, M. Sultan, S. Ata, Adv. Powder Technol. 28 (2017) 2035.10.1016/j.apt.2017.05.008Search in Google Scholar
13. P. A. Carneiro, G. A. Umbuzeiro, D. P. Oliveira, M. V. B. Zanoni, J. Hazard. Mater. 174 (2010) 694.10.1016/j.jhazmat.2009.09.106Search in Google Scholar PubMed
14. H.-W. Gao, J. Bai, X.-M. Pei, H.-Y. Wang, S.-L. Wang, Z. Phys. Chem. 222 (2008) 1635.10.1524/zpch.2008.5400Search in Google Scholar
15. R. Nadeem, Q. Manzoor, M. Iqbal, J. Nisar, J. Indus. Eng. Chem. 35 (2016) 185.10.1016/j.jiec.2015.12.030Search in Google Scholar
16. M. Bilal, M. Iqbal, H. Hu, X. Zhang, Biochem. Eng. J. 109 (2016) 153.10.1016/j.bej.2016.01.020Search in Google Scholar
17. M. Jones, S. Kumar, S. S. Lo, G. D. Scholes, J. Phys. Chem. C. 112 (2008) 5423.10.1021/jp711009hSearch in Google Scholar
18. M. Kousha, E. Daneshvar, M. S. Sohrabi, M. Jokar, A. Bhatnagar, Chem. Eng. J. 192 (2012) 67.10.1016/j.cej.2012.03.057Search in Google Scholar
19. B. Dai, F. Polzer, I. Häusler, Y. Lu, Z. Phys. Chem. 226 (2012) 827.10.1524/zpch.2012.0262Search in Google Scholar
20. J. Khan, M. Sayed, F. Ali, H. M. Khan, Z. Phys. Chem. 232 (2018) 507.10.1515/zpch-2017-1072Search in Google Scholar
21. M. Iqbal, J. Nisar, J. Environ. Chem. Eng. 3 (2015) 1912.10.1016/j.jece.2015.06.011Search in Google Scholar
22. S. Adeel, M. Saeed, A. Abdullah, S. Gull Khan, N. Habib, M. Kamran, M. Zuber, J. Nat. Fibers. (2018) 1. https://doi.org/10.1080/15440478.2018.1458683.10.1080/15440478.2018.1458683Search in Google Scholar
23. S. Adeel, T. Gulzar, M. Azeem, M. Saeed, I. Hanif, N. Iqbal, Radiat. Phys. Chem. 130 (2017) 35.10.1016/j.radphyschem.2016.07.010Search in Google Scholar
24. M. Saeed, A. Haq, M. Muneer, S. Adeel, M. Hamayun, M. Ismail, M. Younas, Glob. Nest J. 18 (2016) 309.10.30955/gnj.001626Search in Google Scholar
25. M. Saeed, S. Adeel, H. Abdur-raoof, M. Usman, A. Mansha, A. Ahmad, M. Amjed, Chiang Mai J. Sci. 44 (2017) 1646.Search in Google Scholar
26. M. A. M. Salleh, D. K. Mahmoud, W. A. W. A. Karim, A. Idris, Desalination. 280 (2011) 1.10.1016/j.desal.2011.07.019Search in Google Scholar
27. R. Nadeem, T. M. Ansari, A. M. Khalid, J. Hazard. Mater. 156 (2008) 64.10.1016/j.jhazmat.2007.11.124Search in Google Scholar PubMed
28. Y. Göksungur, S. Üren, U. Güvenç, Bioresour. Technol. 96 (2005) 103.10.1016/j.biortech.2003.04.002Search in Google Scholar PubMed
29. L. M. Hunt, N. H. Arar, L. L. Akana, J. Family Prac. 49 (2000) 216.Search in Google Scholar
30. Q. Manzoor, R. Nadeem, M. Iqbal, R. Saeed, T. M. Ansari, Bioresour. Technol. 132 (2013) 446.10.1016/j.biortech.2013.01.156Search in Google Scholar PubMed
31. Y. Safa, H. N. Bhatti, Desalination. 272 (2011) 313.10.1016/j.desal.2011.01.040Search in Google Scholar
32. I. Langmuir, J. Am. Chem. Soc. 38 (1916) 2221.10.1021/ja02268a002Search in Google Scholar
33. H. M. F. L. Freundlich, J. Phy. Chem. 57 (1906) 385.Search in Google Scholar
34. S. K. Lagergren, Handingarl. 24 (1898) 1.Search in Google Scholar
35. S. Sadaf, H. N. Bhatti, J. Taiwan Instit. Chem. Eng. 45 (2014) 541.10.1016/j.jtice.2013.05.004Search in Google Scholar
36. A. E. C. Botero, M. L. Torem, L. M. S. de Mesquita, Miner. Eng. 21 (2008) 83.10.1016/j.mineng.2007.08.019Search in Google Scholar
37. S. T. Akar, A. Gorgulu, Z. Kaynak, B. Anilan, T. Akar, Chem. Eng. J. 148 (2009) 26.10.1016/j.cej.2008.07.027Search in Google Scholar
38. Y. Hamzeh, A. Ashori, E. Azadeh, A. Abdulkhani, Mater. Sci. Eng. C. 32 (2012) 1394.10.1016/j.msec.2012.04.015Search in Google Scholar PubMed
39. M. S. Reddy, L. Sivaramakrishna, A. V. Reddy, J. Hazard. Mater. 203 (2012) 118.10.1016/j.jhazmat.2011.11.083Search in Google Scholar PubMed
40. V. K. Gupta, I. Ali, V. K. Saini, Water Res. 41 (2007) 3307.10.1016/j.watres.2007.04.029Search in Google Scholar PubMed
41. Y. Bulut, H. Aydın, Desalination. 194 (2006) 259.10.1016/j.desal.2005.10.032Search in Google Scholar
42. O. Aksakal, H. Ucun, J. Hazard. Mater. 181 (2010) 666.10.1016/j.jhazmat.2010.05.064Search in Google Scholar PubMed
43. V. M. Vučurović, R. N. Razmovski, U. D. Miljić, V. S. Puškaš, J. Taiwan Instit. Chem. Eng. 45 (2014) 1700.10.1016/j.jtice.2013.12.020Search in Google Scholar
44. M. T. Yagub, T. K. Sen, S. Afroze, H. M. Ang, Adv. Colloid Inter. Sci. 209 (2014) 172.10.1016/j.cis.2014.04.002Search in Google Scholar PubMed
45. N. E. Ibisi, C. A. Asoluka, Chem. Int. 4 (2018) 52.Search in Google Scholar
46. S. Jafarinejad, Chem. Int. 3 (2017) 268.Search in Google Scholar
47. K. Legrouri, E. Khouya, H. Hannache, M. El Hartti, M. Ezzine, R. Naslain, Chem. Int. 3 (2017) 301.Search in Google Scholar
48. A. O. Majolagbe, A. A. Adeyi, O. Osibanjo, A. O. Adams, O. O. Ojuri, Chem. Int. 3 (2017) 58.Search in Google Scholar
49. I. Ullah, R. Nadeem, M. Iqbal, Q. Manzoor, Ecol. Eng. 60 (2013) 99.10.1016/j.ecoleng.2013.07.028Search in Google Scholar
50. H. N. Bhatti, A. Jabeen, M. Iqbal, S. Noreen, Z. Naseem, J. Mol. Liq. 237 (2017) 322.10.1016/j.molliq.2017.04.033Search in Google Scholar
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