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Licensed Unlicensed Requires Authentication Published by De Gruyter January 26, 2017

Plasma Assisted Oxidation of Propene

  • Mark C. Hsiao , Bernard T. Merritt , Bernie M. Penetrante , George E. Vogtlin , P. Henrik Wallman , Russell G. Tonkyn , Rahul R. Shah and Thomas M. Orlando

Abstract

Non-thermal plasma processing is an innovative technique for pollutant abatement. This approach involves the use of electrical energy for the production of free radicals which then react with the pollutant molecules. We have studied the oxidation of propene as a prototype hydrocarbon using a packed bed dielectric-barrier discharge reactor to generate the non-thermal plasma. We report the effect of three different types of material filling the reactor: glass, zirconia, and titania. The titania filled reactor shows the greatest selectivity for producing CO2 while the zirconia filled reactor has the greatest yield of total COx. In addition to COx, the plasma assisted oxidation produces small carbon containing compounds like methanol and formaldehyde.

Received: 1995-3-20
Accepted: 1995-6-6
Published Online: 2017-1-26
Published in Print: 1996-1-1

© 2017 by Walter de Gruyter Berlin/Boston

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