Abstract
The title compounds are difunctionalized acetylenic building blocks, which can serve as electrophilic dienophiles and dipolarophiles in [4+2] and azide-iodoalkyne [3+2] cycloaddition reactions, which, however, require strong thermal activation. In their crystal structures, they are self-complementary tectons, which are arranged in polymeric chains maintained by very short intermolecular Csp–I···O=P halogen bonds.
Acknowledgements
We thank B. Müller (Institute of Inorganic Chemistry II) for the X-ray diffraction data collection and Dr. M. Wunderlin for the mass spectra.
Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
Research funding: Ulm University.
Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
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