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Abstract
The paper describes attempts to detect interactions or encounter complexes between reacting molecules, although the individual molecules might not succeed in forming a reaction product. As an example, the Diels-Alder reaction is chosen, and the technique employed comprises NMR T1 and NMR NOE measurements. In the case of the intermolecular Diels-Alder reaction both methods were not successful, in the intramolecular Diels-Alder reaction NOE results are able to predict the stereochemical outcome.
Published Online: 2009-9-25
Published in Print: 2008-8-1
© by Oldenbourg Wissenschaftsverlag, München, Germany
